Home > Name List By n > Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,...

CAS No 639-86-1 , Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-

  • Name: Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-
  • Synonyms: Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-, [2S-(2a,4aa,4bb,6aa,6bb,7b,7ab,10b,11aa,12aa,13ab,13ba,15ab)]-; 3b-Amino-22,26-imino-16b,23-oxido-5a,22R,23S,25R-cholestan-23-ol; Solanocapsin;Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-; NSC102622; 3b-Amino-22,26-epimino-16a,23-epoxy-5a,22aH,25bH-cholestan-23b-ol; Solanocapsine (6CI,7CI,8CI);16,28-Secosolanidan-23-ol,3-amino-16,23-epoxy-, (3b,5a,16a,22a,23b,25b)-;
  • CAS Registry Number:
  • Flash Point: 283.9°C
  • Boiling Point: 545.8°Cat760mmHg
  • Density: 1.064g/cm3
  • Refractive index: 1.53
  • Flash Point: 283.9°C
  • Molecular Weight: 430.6663
  • InChI: InChI=1/C27H46N2O2/c1-15-13-27(30)24(29-14-15)16(2)23-22(31-27)12-21-19-6-5-17-11-18(28)7-9-25(17,3)20(19)8-10-26(21,23)4/h15-24,29-30H,5-14,28H2,1-4H3/t15-,16+,17+,18+,19-,20+,21+,22-,23+,24-,25+,26+,27+/m1/s1
  • Molecular Formula: C27H46 N2 O2
  • Molecular Structure:CAS No:639-86-1 Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-

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639-86-1 Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-

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References of Naphth[2'',1'':4',5']indeno[1',2':5,6]pyrano[3,2-b]pyridin-11a(1H)-ol,2-aminodocosahydro-4a,6a,7,10-tetramethyl-,(2S,4aS,4bS,6aS,6bR,7S,7aR,10R,11aS,12aR,13aS,13bR,15aS)-
Title: Solanocapsine
CAS Registry Number: 639-86-1
CAS Name: (3b,5a,16a,22a,23b,25b)-3-Amino-16,23-epoxy-16,28-secosolanidan-23-ol
Synonyms: solanocapsin; 3b-amino-22,26-imino-16b,23-oxido-5a,22a,23b,25a-cholestan-23-ol; 3b-amino-22,26-imino-16b,23-oxido-5a,22R,23S,25R-cholestan-23-ol
Molecular Formula: C27H46N2O2
Molecular Weight: 430.67
Percent Composition: C 75.30%, H 10.77%, N 6.50%, O 7.43%
Literature References: From Solanum pseudocapsicum L., S. capsicastrum Link, S. hendersonii hort., Solanaceae. Isolation: Barger, Fraenkel-Conrat, J. Chem. Soc. 1936, 1537; K. Schreiber, H. Ripperger, Z. Naturforsch. 17B, 217 (1962). Structure: eidem, Experientia 16, 536 (1960). Revised structure and synthesis: eidem, Ann. 723, 159 (1969). Stereochemistry: eidem, Tetrahedron Letters no. 27, 9 (1960); Ann. 655, 114 (1962). Synthesis: Ripperger et al., Tetrahedron Lett. 1970, 5251; eidem, Tetrahedron 28, 1629 (1972).
Properties: Monohydrate, needles from methanol, mp 213-215°. [a]D20 +26.3° (c = 1.80 in methanol); [a]D20 +24.9° (c = 2.13 in methanol).
Melting point: mp 213-215°
Optical Rotation: [a]D20 +26.3° (c = 1.80 in methanol); [a]D20 +24.9° (c = 2.13 in methanol)
 
Derivative Type: N￠-Acetylsolanocapsine
Molecular Formula: C29H48N2O3
Molecular Weight: 472.70
Percent Composition: C 73.69%, H 10.24%, N 5.93%, O 10.15%
Properties: Needles from ethanol, mp 233-234°. [a]D23 -33.7° (c = 1.59 in pyridine).
Melting point: mp 233-234°
Optical Rotation: [a]D23 -33.7° (c = 1.59 in pyridine)
 
Derivative Type: N,N￠-Diacetylsolanocapsine
Molecular Formula: C31H50N2O4
Molecular Weight: 514.74
Percent Composition: C 72.33%, H 9.79%, N 5.44%, O 12.43%
Properties: Crystals from chloroform + acetone, mp 281-283°. [a]D22 -38.6° (c = 1.31 in pyridine).
Melting point: mp 281-283°
Optical Rotation: [a]D22 -38.6° (c = 1.31 in pyridine)
 
Derivative Type: N,N,N￠-Trimethylsolanocapsine
Molecular Formula: C30H52N2O2
Molecular Weight: 472.75
Percent Composition: C 76.22%, H 11.09%, N 5.93%, O 6.77%
Properties: Needles from abs methanol, mp 222-224°. [a]D22 +53.2° (c = 1.09 in pyridine).
Melting point: mp 222-224°
Optical Rotation: [a]D22 +53.2° (c = 1.09 in pyridine)
 
Derivative Type: N-Benzylidenesolanocapsine
Molecular Formula: C34H50N2O2
Molecular Weight: 518.77
Percent Composition: C 78.72%, H 9.71%, N 5.40%, O 6.17%
Properties: Needles from pyridine + abs methanol, mp 249-251°. [a]D18 +31.4° (c = 0.78 in pyridine).
Melting point: mp 249-251°
Optical Rotation: [a]D18 +31.4° (c = 0.78 in pyridine)