Home > Name List By 3 > 3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]flu...

CAS No 60-70-8 , 3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]fluoren-9-yl]ethyl]-,(2S,3R,5S)-

  • Name: 3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]fluoren-9-yl]ethyl]-,(2S,3R,5S)-
  • Synonyms: NSC 17821;Veratraman-3,23-diol,14,15,16,17-tetradehydro-, (3b,23b)-;3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]fluoren-9-yl]ethyl]-,(2S,3R,5S)-; Veratramine (7CI,8CI); NSC 23880;1H-Benzo[a]fluorene, veratraman-3,23-diol deriv.;
  • CAS Registry Number:
  • Melting Point: 122-1240C
  • Flash Point: 86.2°C
  • Boiling Point: 565°C at 760 mmHg
  • Density: 1.14g/cm3
  • Refractive index: 1.601
  • Safety Statements: Poison by ingestion, intravenous, and subcutaneous routes. An experimental teratogen. When heated to decomposition it emits toxic fumes of NOx.
  • Flash Point: 86.2°C
  • Molecular Weight: 409.67
  • InChI: InChI=1/C27H39NO2/c1-15-11-25(30)26(28-14-15)17(3)20-7-8-21-22-6-5-18-12-19(29)9-10-27(18,4)24(22)13-23(21)16(20)2/h5,7-8,15,17,19,22,24-26,28-30H,6,9-14H2,1-4H3
  • Molecular Formula: C27H39 N O2
  • Molecular Structure:CAS No:60-70-8 3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]fluoren-9-yl]ethyl]-,(2S,3R,5S)-

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60-70-8 Veratramine

  • Veratramine Type: Veratrum nigrum Extract Form: Liquid Colour: Deep brown Active ingredient: veratramine CAS: 60-70-8 MF: C27H39NO2 MW: 409.61 Assay: 0.8% Package: 25kg/drum Application: Natural pest control Period & Dosage: Dilute the botanical with...
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60-70-8 Veratramine

  • Product Name: Veratramine CAS No.: 60-70-8 Molecular Formula: C27H39NO2 Molecular Weight: 409.60 Appearance: White Solid Solubility: Soluble in Ethanol and Methanol Purity: >98% by HPLC
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References of 3-Piperidinol,5-methyl-2-[(1S)-1-[(3S,6aR,11aS,11bR)-2,3,4,6,6a,11,11a,11b-octahydro-3-hydroxy-10,11b-dimethyl-1H-benzo[a]fluoren-9-yl]ethyl]-,(2S,3R,5S)-
Title: Veratramine
CAS Registry Number: 60-70-8
CAS Name: (3b,23b)-14,15,16,17-Tetradehydroveratraman-3,23-diol
Molecular Formula: C27H39NO2
Molecular Weight: 409.60
Percent Composition: C 79.17%, H 9.60%, N 3.42%, O 7.81%
Literature References: Secondary base from Veratrum grandiflorum (Maxim.) Loes. f., and from V. viride Ait., Liliaceae. Isoln and structure: Saito, Bull. Chem. Soc. Jpn. 15, 22 (1940); Jacobs, Craig, J. Biol. Chem. 160, 555 (1945); Jacobs, Sato, ibid. 181, 55 (1949); 191, 71 (1951); Tamm, Wintersteiner, J. Am. Chem. Soc. 74, 3842 (1952); Wintersteiner, Festschrift Arthur Stoll (Birkh?user-Verlag, Basel) pp 166-176. Total synthesis: Masamune et al., J. Am. Chem. Soc. 89, 4521 (1967); Johnson et al., ibid. 4523; Masamune et al., Tetrahedron 27, 3369 (1971); Kutney et al., Can. J. Chem. 53, 1796 (1975). Stereochemistry: Sicher, Tichy, Tetrahedron Lett. 1959(12), 6 (1959); Kataoka, Chem. Ind. (London) 1961, 512; Bailey et al., Tetrahedron Lett. 1963, 555. Revised stereochemistry: Scott et al., ibid. 1967, 2381; Kupchan, Suffness, J. Am. Chem. Soc. 90, 2730 (1968); Sprague et al., Tetrahedron 27, 4857 (1971). See also: Veratrum Viride.
Properties: Crystals, mp 206-207°. Slightly sol in water. Sol in methanol, alcohol. Precipitated by digitonin. [a]D25 -71.8° (c = 1.21); [a]D25 -70° (c = 1.56 in methanol). uv max: 268 nm.
Melting point: mp 206-207°
Optical Rotation: [a]D25 -71.8° (c = 1.21); [a]D25 -70° (c = 1.56 in methanol)
Absorption maximum: uv max: 268 nm
 
Derivative Type: Dihydroveratramine
Properties: Crystals, mp 192.5-194°. [a]D25 +26° (c = 1.26 in acetic acid).
Melting point: mp 192.5-194°
Optical Rotation: [a]D25 +26° (c = 1.26 in acetic acid)