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CAS No 533-74-4 , 3,5-dimethyl-1,3,5-thiadiazinane-2-thione

  • Name: 3,5-dimethyl-1,3,5-thiadiazinane-2-thione
  • Synonyms: Thiazone;3,5-dimethyl-1,3,5-thiadiazinane-2-thione; Carbothialdin; Basamide; Mylone; Dimethylformocarbothialdine; Nefusan;Basamid; DMTT; Tiazon;
  • CAS Registry Number:
  • Transport: UN3077 9/PG 3
  • Melting Point: 104-105 ºC
  • Density: 1.3
  • Refractive index: 1.655
  • Water Solubility: <0.1 G/100 ML AT 18 ºC
  • Safety Statements: Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact and subcutaneous routes. A severe eye irritant. A mild primary skin irritant and sensitizer. When heated to decomposition it emits very toxic fumes of NOx and SOx.
  • Hazard Symbols: Toxic by ingestion and inhalation.
  • EINECS: 208-576-7
  • Molecular Weight: 162.2763
  • InchiKey: QAYICIQNSGETAS-UHFFFAOYSA-N
  • InChI: InChI=1S/C5H10N2S2/c1-6-3-7(2)5(8)9-4-6/h3-4H2,1-2H3
  • Risk Statements: 22-36-50/53
  • Molecular Formula: C5H10N2S2
  • Molecular Structure:CAS No:533-74-4 3,5-dimethyl-1,3,5-thiadiazinane-2-thione

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References of 3,5-dimethyl-1,3,5-thiadiazinane-2-thione
Title: Dazomet
CAS Registry Number: 533-74-4
CAS Name: Tetrahydro-3,5-dimethyl-2H-1,3,5-thiadiazine-2-thione
Synonyms: 2-thio-3,5-dimethyltetrahydro-1,3,5-thiadiazine; 3,5-dimethyl-2-thionotetrahydro-1,3,5-thiadiazine; dimethylformocarbothialdine; DMTT
Manufacturers' Codes: UCC 974
Trademarks: Crag 974; Mylone
Molecular Formula: C5H10N2S2
Molecular Weight: 162.28
Percent Composition: C 37.01%, H 6.21%, N 17.26%, S 39.52%
Literature References: Prepd by the action of carbon disulfide on trimethyltrimethylenetriimine: Delépine, Bull. Soc. Chim. 15, 891 (1897); from formaldehyde and methylammonium methyldithiocarbamate: Bodendorf, J. Prakt. Chem. 126, 233 (1930); Ainley et al., J. Chem. Soc. 1944, 147. Prepd commercially by the reaction of carbon disulfide, methylamine and caustic soda: Chem. Week 79, no. 18, 82-83 (1956). Toxicology study: H. F. Smyth, Jr. et al., Toxicol. Appl. Pharmacol. 9, 521 (1966).
Properties: Needles from benzene, mp 106-107°. Soluble in alc with decompn. Dec by water, dil acids. uv max (cyclohexane): 242, 289 nm (e 7150, 9900). LD50 in rats, mice, guinea pigs, rabbits (g/kg): 0.32-0.62, 0.18, 0.16, 0.12 orally; in rats, rabbits, dogs (g/kg): 0.087, 0.127, 0.047-0.063 i.p.; in rabbits (g/kg): 7.1 dermally (Smyth).
Melting point: mp 106-107°
Absorption maximum: uv max (cyclohexane): 242, 289 nm (e 7150, 9900)
Toxicity data: LD50 in rats, mice, guinea pigs, rabbits (g/kg): 0.32-0.62, 0.18, 0.16, 0.12 orally; in rats, rabbits, dogs (g/kg): 0.087, 0.127, 0.047-0.063 i.p.; in rabbits (g/kg): 7.1 dermally (Smyth)
Use: Soil fungicide, nematocide, weed killer; slimicide in paper making.