Home > Name List By other > (3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4, 5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7...

CAS No 36069-05-3 , (3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7,8,
11a-decahydrobenzo[a]fluorene-9,2'-3a,4,5,6,7,7a-hexahydro-3H-furo[3,
2-b]pyridine]-11-one

  • Name: (3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7,8,
    11a-decahydrobenzo[a]fluorene-9,2'-3a,4,5,6,7,7a-hexahydro-3H-furo[3,
    2-b]pyridine]-11-one
  • Synonyms: Jervin-3-glucoside;Pseudojervin; JERVINE; 3-beta-(D-GLUCOPYRANOSYLOXY)-; BRN 0072750; AC1L1XKL; O-beta-D-Glucopyranosyljervine;(3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7,8,
    11a-decahydrobenzo[a]fluorene-9,2'-3a,4,5,6,7,7a-hexahydro-3H-furo[3,
    2-b]pyridine]-11-one;
  • CAS Registry Number:
  • Flash Point: 417.2°C
  • Boiling Point: 766.2°Cat760mmHg
  • Density: 1.32g/cm3
  • Refractive index: 1.616
  • Flash Point: 417.2°C
  • Molecular Weight: 587.74406
  • InchiKey: HYDDDNUKNMMWBD-WJWSUNTISA-N
  • InChI: InChI=1S/C33H49NO8/c1-15-11-22-26(34-13-15)17(3)33(42-22)10-8-20-21-6-5-
    18-12-19(40-31-30(39)29(38)27(36)23(14-35)41-31)7-9-32(18,
    4)25(21)28(37)24(20)16(33)2/h5,15,17,19-23,25-27,29-31,34-36,38-39H,
    6-14H2,1-4H3/t15?,17?,19-,20?,21?,22+,23?,25?,26-,27+,29?,30?,31+,32?,
    33-/m0/s1
  • Molecular Formula: C33H49NO8
  • Molecular Structure:CAS No:36069-05-3 (3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4,<br />5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7,8,<br />11a-decahydrobenzo[a]fluorene-9,2'-3a,4,5,6,7,7a-hexahydro-3H-furo[3,<br />2-b]pyridine]-11-one

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References of (3S,3'aS,7'aR,9R)-3',6',10,11b-tetramethyl-3-[(2R,5S)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyspiro[1,2,3,4,6,6a,6b,7,8,
11a-decahydrobenzo[a]fluorene-9,2'-3a,4,5,6,7,7a-hexahydro-3H-furo[3,
2-b]pyridine]-11-one
Title: Pseudojervine
CAS Registry Number: 36069-05-3
CAS Name: (3b,23b)-17,23-Epoxy-3-(b-D-glucopyranosyloxy)veratraman-11-one
Molecular Formula: C33H49NO8
Molecular Weight: 587.74
Percent Composition: C 67.44%, H 8.40%, N 2.38%, O 21.78%
Literature References: Glucoside of jervine. Isoln from Veratrum album L., Liliaceae: Wright, Luff, J. Chem. Soc. 35, 405 (1879); Poethke, Arch. Pharm. 276, 170 (1938); from V. viride Ait., Liliaceae: Jacobs, Craig, J. Biol. Chem. 155, 565 (1944); from V. eschscholtzii Gray, Liliaceae: Klohs et al., J. Am. Chem. Soc. 75, 2133 (1953).
Properties: Lustrous leaflets. mp 300-301° (dec). [a]D25 -133° (c = 0.48 in 1:3 ethanol-chloroform). Sol in chloroform, benzene; slightly sol in alcohol. Almost insol in ether.
Melting point: mp 300-301° (dec)
Optical Rotation: [a]D25 -133° (c = 0.48 in 1:3 ethanol-chloroform)
 
 
Status: This monograph has been retired and is no longer subject to revision or update.