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CAS No 99105-77-8 , 2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione

  • Name: 2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione
  • Synonyms: 2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione;99105-77-8; 114680-61-4; 2-(2-chloro-4-mesylbenzoyl)cyclohexane-1,3-dione;2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione;
  • CAS Registry Number:
  • Melting Point: 139ºC
  • Density: 1.428 g/cm3
  • Refractive index: 1.571
  • Safety Statements: R43
  • Hazard Symbols: Xi: Irritant;
  • Molecular Weight: 328.76802
  • InchiKey: PQTBTIFWAXVEPB-UHFFFAOYSA-N
  • InChI: InChI=1S/C14H13ClO5S/c1-21(19,
    20)8-5-6-9(10(15)7-8)14(18)13-11(16)3-2-4-12(13)17/h5-7,13H,2-4H2,1H3
  • Risk Statements: S36/37
  • Molecular Formula: C14H13ClO5S
  • Molecular Structure:CAS No:99105-77-8 2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione

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References of 2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione
Title: Sulcotrione
CAS Registry Number: 99105-77-8
CAS Name: 2-[2-Chloro-4-(methylsulfonyl)benzoyl]-1,3-cyclohexanedione
Manufacturers' Codes: ICIA-0051; SC-0051
Trademarks: Mikado (Bayer CropSci.)
Molecular Formula: C14H13ClO5S
Molecular Weight: 328.77
Percent Composition: C 51.15%, H 3.99%, Cl 10.78%, O 24.33%, S 9.75%
Literature References: Triketone bleaching herbicide for use in maize. Inhibits 4-hydroxyphenylpyruvate dioxygenase, an enzyme involved in the biosynthesis of plastoquinones. Prepn: W. J. Michaely, G. W. Kraatz, EP 137963; eidem, US 4780127 (1983, 1988 both to Stauffer Chem.). Field trials in corn: J. S. Wilson, C. L. Foy, Weed Technol. 4, 731 (1990). Soil adsorption: eidem, ibid. 6, 583 (1992). Mode of action study: J. Secor, Plant Physiol. 106, 1429 (1994). Comprehensive description: J. M. Beraud et al., Brighton Crop Prot. Conf. - Weeds 1991, 51-56.
Properties: Light tan solid, mp 139°. Vapor pressure (25°): 4 ′ 10-8 mm Hg. Soly in water (25°): 165 mg/l. Sol in acetone, chlorobenzene.
Melting point: mp 139°
Use: Herbicide.