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CAS No 7658-08-4 , (2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal

  • Name: (2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal
  • Synonyms: 6OG; CHEBI:28140;(2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal; AC1L3QHH; AC1Q6A76;6-Deoxy-D-glucose; D-Qui; 7658-08-4; 6DOG; D-Glucose; 6-Deoxyglucose; 6-deoxy-;
  • CAS Registry Number:
  • Density: 1.41 g/cm3
  • Refractive index: 1.593
  • Water Solubility: H2O: 10 mg/mL, clear, colorless
  • EINECS: 231-622-2
  • Molecular Weight: 164.15648
  • InchiKey: PNNNRSAQSRJVSB-JGWLITMVSA-N
  • InChI: InChI=1S/C6H12O5/c1-3(8)5(10)6(11)4(9)2-7/h2-6,8-11H,1H3/t3-,4+,5-,
    6-/m1/s1
  • Molecular Formula: C6H12O5
  • Molecular Structure:CAS No:7658-08-4 (2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal

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References of (2R,3S,4R,5R)-2,3,4,5-tetrahydroxyhexanal
Title: Quinovose
CAS Registry Number: 7658-08-4
CAS Name: 6-Deoxy-D-glucose
Synonyms: D-glucomethylose; D-isorhamnose; D-epirhamnose; isorhodeose; epifucose; chinovose
Molecular Formula: C6H12O5
Molecular Weight: 164.16
Percent Composition: C 43.90%, H 7.37%, O 48.73%
Literature References: Isoln from cinchona bark: Freudenerg, Ber. 62, 373 (1929). Identity with D-glucomethylose: Votocek, Rác, Collect. Czech. Chem. Commun. 1, 239 (1929). Structure: Karrer, Boettcher, Helv. Chim. Acta 36, 570 (1953). Synthesis from 6-O-p-tolylsulfonyl-D-glucose: Schmidt, "6-Deoxy-a-D-glucose" in Methods in Carbohydrate Chemistry vol. I, R. L. Whistler, M. L. Wolfrom, Eds. (Academic Press, New York, 1962) pp 198-201. Alternate facile synthesis: V. K. Srivastava, L. M. Lerner, Carbohydr. Res. 64, 263 (1978).
Properties: Crystals from ethyl acetate, mp 146°. [a]D20 +73° (5 min) ? +30° (3 hr, final) (c = 8.3 in water). Sol in water, ethanol. Practically insol in ether, acetone.
Melting point: mp 146°
Optical Rotation: [a]D20 +73° (5 min) ? +30° (3 hr, final) (c = 8.3 in water)