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CAS No 568-21-8 , 4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (6aS)-

  • Name: 4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (6aS)-
  • Synonyms: Isothebaine (6CI,7CI); (+)-Isothebaine; 2,11-Dimethoxy-6aa-aporphin-1-ol;4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (6aS)-;4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (S)-; 1-Hydroxy-2,11-dimethoxy-6aa-aporphine; NSC 290957; 6aa-Aporphin-1-ol, 2,11-dimethoxy-(8CI);
  • CAS Registry Number:
  • Flash Point: 249.6°C
  • Boiling Point: 489.2°Cat760mmHg
  • Density: 1.219g/cm3
  • Refractive index: 1.617
  • Flash Point: 249.6°C
  • Molecular Weight: 311.37
  • InChI: InChI=1/C19H21NO3/c1-20-8-7-12-10-15(23-3)19(21)18-16(12)13(20)9-11-5-4-6-14(22-2)17(11)18/h4-6,10,13,21H,7-9H2,1-3H3/t13-/m0/s1
  • Molecular Formula: C19H21 N O3
  • Molecular Structure:CAS No:568-21-8 4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (6aS)-

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568-21-8 ISOTHEBAINE(RG)

  • ISOTHEBAINE(RG)Isothebaine
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References of 4H-Dibenzo[de,g]quinolin-1-ol,5,6,6a,7-tetrahydro-2,11-dimethoxy-6-methyl-, (6aS)-
Title: Isothebaine
CAS Registry Number: 568-21-8
CAS Name: (6aS)-5,6,6a,7-Tetrahydro-2,11-dimethoxy-6-methyl-4H-dibenzo[de,g]quinolin-1-ol
Synonyms: 2,11-dimethoxy-6aa-aporphin-1-ol; 1-hydroxy-2,11-dimethoxyaporphine
Molecular Formula: C19H21NO3
Molecular Weight: 311.37
Percent Composition: C 73.29%, H 6.80%, N 4.50%, O 15.42%
Literature References: Occurs as d-form in the root and whole plant of Papaver orientale L., Papaveraceae, collected in late autumn. Isoln: Gadamer, Arch. Pharm. 249, 39 (1911). Structure: Bentley, Blues, J. Chem. Soc. 1956, 1732; Bentley, Dyke, J. Org. Chem. 22, 429 (1957). Synthesis of dl-form: Battersby, Brown, Proc. Chem. Soc. London 1964, 85; H. Hara et al., Chem. Pharm. Bull. 29, 1083 (1981). Synthesis of natural and racemic forms: Battersby et al., J. Chem. Soc. 1965, 4550. Biosynthesis: eidem, Chem. Commun. 1965, 230.
Properties: Light-sensitive, rhombic crystals. mp 203-204°. [a]D18 +285° in alc. Sol in alcohol, chloroform, slightly in ether.
Melting point: mp 203-204°
Optical Rotation: [a]D18 +285° in alc