Home > Name List By 2 > 2-methyl-2-[(2S,3R,4S,5S,6R)-3,4, 5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile

CAS No 554-35-8 , 2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile

  • Name: 2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile
  • Synonyms: 554-35-8; BRN 0019237; HSDB 3507;Phaseolunatin;2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile; 2-(beta-D-Glucopyranosyloxy)-2-methylpropanenitrile;
  • CAS Registry Number:
  • Flash Point: 240°C
  • Boiling Point: 473.3°Cat760mmHg
  • Density: 1.41g/cm3
  • Refractive index: 1.549
  • Safety Statements: Moderately toxic by ingestion. An experimental teratogen. When heated to decomposition it emits toxic fumes of NOx.
  • Hazard Symbols: Xn
  • Flash Point: 240°C
  • Molecular Weight: 247.24508
  • InchiKey: QLTCHMYAEJEXBT-ZEBDFXRSSA-N
  • InChI: InChI=1S/C10H17NO6/c1-10(2,4-11)17-9-8(15)7(14)6(13)5(3-12)16-9/h5-9,
    12-15H,3H2,1-2H3/t5-,6-,7+,8-,9+/m1/s1
  • Risk Statements: 20/22-36/37/38
  • Molecular Formula: C10H17NO6
  • Molecular Structure:CAS No:554-35-8 2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,<br />5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile

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554-35-8 2-(-D-GLUCOPYRANOSYLOXY)-2-METHYL-PROPANENITRILE; PHASEOLUNATIN =LINAMARIN

  • Germany CHEMOS GmbH [Manufacturer]
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554-35-8 A2060 LINAMARIN

  • United Kingdom Carbosynth Limited [Manufacturer]
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554-35-8 LINAMARIN(RG)

  • United States ChromaDex Inc. [Manufacturer]
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554-35-8 LINAMARIN ( 2-(BETA-D-GLUCOPYRANOSYLOXY)-2-METHYL-PROPANENITRILE )

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References of 2-methyl-2-[(2S,3R,4S,5S,6R)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropanenitrile
Title: Linamarin
CAS Registry Number: 554-35-8
CAS Name: 2-(b-D-Glucopyranosyloxy)-2-methylpropanenitrile
Synonyms: phaseolunatin
Molecular Formula: C10H17NO6
Molecular Weight: 247.25
Percent Composition: C 48.58%, H 6.93%, N 5.66%, O 38.83%
Literature References: From the seed skins or embryos of flax: Jorissen, Hairs, Bull. Acad. Roy. Sci. Belg. [3] 21, 529 (1891); André et al., Compt. Rend. 231, 590 (1950); Lüdtke, Biochem. Z. 323, 428 (1953). Synthesis: Fischer, Anger, Ber. 52, 854 (1919). Biosynthesis in white clover: Butler, Butler, Nature 187, 780 (1960).
Properties: Bitter needles, mp 142-143°. [a]D18 -29°. Freely sol in water, cold alcohol, hot acetone; slightly in hot ethyl acetate, ether, benzene, chloroform. Practically insol in petr ether. Evolves HCN with linseed meal but not with emulsin.
Melting point: mp 142-143°
Optical Rotation: [a]D18 -29°
 
Derivative Type: Tetraacetate
Molecular Formula: C18H25NO10
Molecular Weight: 415.39
Percent Composition: C 52.05%, H 6.07%, N 3.37%, O 38.52%
Properties: Needles from alcohol, mp 140-141°. [a]D14 -10.8° (acetone). Sol in acetone, ethyl acetate, chloroform, glacial acetic acid, benzene, warm methanol and ethanol. Practically insol in petr ether.
Melting point: mp 140-141°
Optical Rotation: [a]D14 -10.8° (acetone)