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CAS No 522-97-4 , Canadine

  • Name: Canadine
  • Synonyms: dl-Canadine;Canadine; Berberine; tetrahydro-; Canadin; Tetrahydroberberine; (+-)-Tetrahydroberberine; Xanthopuccine; CHEBI:22998; Canadine dl-form;
  • CAS Registry Number:
  • Density: 1.33 g/cm3
  • Water Solubility: DMSO: >10 mg/mL, soluble
  • Safety Statements: 36
  • Hazard Symbols: Xn: Harmful;
  • EINECS: 208-338-2
  • Molecular Weight: 339.38504
  • InchiKey: VZTUIEROBZXUFA-UHFFFAOYSA-N
  • InChI: InChI=1S/C20H21NO4/c1-22-17-4-3-12-7-16-14-9-19-18(24-11-25-19)8-13(14)
    5-6-21(16)10-15(12)20(17)23-2/h3-4,8-9,16H,5-7,10-11H2,1-2H3
  • Risk Statements: 22
  • Molecular Formula: C20H21NO4
  • Molecular Structure:CAS No:522-97-4 Canadine

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522-97-4 TETRAHYDROBERBERINE(CANADINE)(P)

  • TETRAHYDROBERBERINE(CANADINE)(P)DL-Canadine
  • United States ChromaDex Inc. [Manufacturer]
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522-97-4 Canadine

  • China Shanghai Xunxin Chemical Co., Ltd [Manufacturers]
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  • Address: 580 Lane, Kanghong Road, Pudong New District, Shanghai 201315, Shanghai,ShanghaiChina
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522-97-4 Canadine

  • China Laiwu Hehui Chemical Co.,Ltd. null
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522-97-4 6H-Benzo[g]-1,3-benzodioxolo[5,6-a]quinolizine,5,8,13,13a-tetrahydro-9,10-dimethoxy-

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522-97-4 DL-Tetrahydroberberine

  • DL-Tetrahydroberberine
  • Germany CHEMOS GmbH [Manufacturer]
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  • Address: CHEMOS GmbH
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522-97-4 (D,L)-TETRAHYDROBERBERINE

  • (D,L)-TETRAHYDROBERBERINE
  • Hong kong Advanced Technology & Industrial Co., Ltd. [Manufacturer]
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References of Canadine
Title: Canadine
CAS Registry Number: 522-97-4
CAS Name: 5,8,13,13a-Tetrahydro-9,10-dimethoxy-6H-benzo[g]-1,3-benzodioxolo[5,6-a]quinolizine
Synonyms: 9,10-dimethoxy-2,3-(methylenedioxy)berbine; 5,6,13,13a-tetrahydro-9,10-dimethoxy-2,3-(methylenedioxy)-8H-dibenzo[a,g]quinolizine; tetrahydroberberine; xanthopuccine
Molecular Formula: C20H21NO4
Molecular Weight: 339.39
Percent Composition: C 70.78%, H 6.24%, N 4.13%, O 18.86%
Literature References: A protoberberine alkaloid from Corydalis cava (L.), Schweigg & Korte (C. tuberosa DC.), Fumariaceae: Sp?th, Julian, Ber. 64, 1131 (1931). Prepn by reduction of berberine: Bersch, Seufert, ibid. 70, 1121 (1937); Awe, Hertel, Arch. Pharm. 288, 516 (1955); Russell, J. Am. Chem. Soc. 78, 3115 (1956). Configuration: Corrodi, Hardegger, Helv. Chim. Acta 39, 889 (1956). Other syntheses: Kametani et al., J. Chem. Soc. C 1969, 2036; 1971, 2709; M. Cushman, F. W. Dekon, J. Org. Chem. 44, 407 (1979); K. Iwasa et al., ibid. 46, 4744 (1981); N. S. Narasimhan et al., Tetrahedron Lett. 22, 2797 (1981). Pharmacology: F. Sadritdinov, M. B. Sultanov, C.A. 66, 74714v (1967). Review: R. H. F. Manske, H. L. Holmes, The Alkaloids vol. 4 (Academic Press, New York, 1954) pp 91-92.
Properties: LD50 in mice (mg/kg): 940 orally; 790 s.c.; 100 i.v. (Sadritdinov, Sultanov).
Toxicity data: LD50 in mice (mg/kg): 940 orally; 790 s.c.; 100 i.v. (Sadritdinov, Sultanov)
 
Derivative Type: d-Form
CAS Registry Number: 2086-96-6
Properties: mp 132°. [a]D15 +299° (chloroform). Sol in aq methanol.
Melting point: mp 132°
Optical Rotation: [a]D15 +299° (chloroform)
 
Derivative Type: l-Form
CAS Registry Number: 5096-57-1
Properties: Crystals from methanol, mp 135°. [a]D22 -308°; -317° (c = 0.28; 0.4, both in methanol). Sol in aq methanol.
Melting point: mp 135°
Optical Rotation: [a]D22 -308°; -317° (c = 0.28; 0.4, both in methanol)
 
Derivative Type: dl-Form
CAS Registry Number: 29074-38-2
Properties: mp 172° (Sp?th, Julian), also reported as 163-165° (Cushman, Dekon). uv max (95% ethanol): 209, 284 nm (e 28,300; 5200). Sol in aq methanol.
Melting point: mp 172° (Sp?th, Julian), also reported as 163-165° (Cushman, Dekon)
Absorption maximum: uv max (95% ethanol): 209, 284 nm (e 28,300; 5200)