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CAS No 494-52-0 , L(-)-Anabasine

  • Name: L(-)-Anabasine
  • Synonyms: (-)-Neonicotine~(S)-3-(2-Piperidinyl)pyridine;(-)-Anabasine; 2-(3-pyridyl)piperidine; 3-(2-Piperidyl)-pyridine;L(-)-Anabasine;
  • CAS Registry Number:
  • Transport: 3140
  • Density: 1.054
  • Refractive index: 1.5430
  • Safety Statements: R23/24/25,
  • Hazard Symbols: T:Toxic;
  • EINECS: 207-791-3
  • Molecular Weight: 162.23
  • InChI: InChI=1/C10H14N2/c1-2-7-12-10(5-1)9-4-3-6-11-8-9/h3-4,6,8,10,12H,1-2,5,7H2
  • Risk Statements: S28A,S36/37/39,S45,
  • Molecular Formula: C10H14N2
  • Molecular Structure:CAS No:494-52-0 L(-)-Anabasine

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References of L(-)-Anabasine
Title: Anabasine
CAS Registry Number: 494-52-0
CAS Name: 3-(2-Piperidinyl)pyridine
Synonyms: 2-(3-pyridyl)piperidine; neonicotine
Molecular Formula: C10H14N2
Molecular Weight: 162.23
Percent Composition: C 74.04%, H 8.70%, N 17.27%
Literature References: In Anabasis aphylla L., Chenopodiaceae: Orechoff, Menschikoff, Ber. 64, 266 (1931); in Nicotiana glauca Graham, Solanaceae: Smith, J. Am. Chem. Soc. 57, 959 (1935); Pyriki, Oehler, Pharmazie 9, 685 (1954). Synthesis: Sp?th, Ber. 70B, 70 (1937). Extracted on a large scale in Russia. Industrial extraction processes: Sadykov, Timbekov, J. Appl. Chem. USSR 29, 148 (1956). Abs config: Lukes et al., Collect. Czech. Chem. Commun. 27, 751 (1962).
Properties: Liquid, bp 270-272°; bp14 145-147°; bp2 105°. Freezes at 9°. d420 1.0455. nD20 1.5430. [a]D20 -83.1°. Sol in water and in most organic solvents.
Boiling point: bp 270-272°; bp14 145-147°; bp2 105°
Optical Rotation: [a]D20 -83.1°
Index of refraction: nD20 1.5430
Density: d420 1.0455
 
Derivative Type: Hydrochloride
Properties: [a]D +16.5° (c = 10 in water).
Optical Rotation: [a]D +16.5° (c = 10 in water)
 
CAUTION: Acute and subacute toxicity: increased salivation, vertigo, confusion, disturbed vision and hearing, photophobia, cold extremities, nausea, vomiting, diarrhea, syncope, clonic spasms.
Use: Insecticide.