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CAS No 41394-05-2 , 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-one

  • Name: 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-one
  • Synonyms: Goltix; 41394-05-2; Herbrak; Metamiton; 4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5-one; Metamitron [German]; Methiamitron [French];4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-one;
  • CAS Registry Number:
  • Transport: UN 3077
  • Melting Point: 167-170 ºC
  • Density: 1.34 g/cm3
  • Refractive index: 1.672
  • Safety Statements: R22;R50
  • Hazard Symbols: Xn: Harmful;N: Dangerous for the environment;
  • EINECS: 255-349-3
  • Molecular Weight: 202.2126
  • InchiKey: VHCNQEUWZYOAEV-UHFFFAOYSA-N
  • InChI: InChI=1S/C10H10N4O/c1-7-12-13-9(10(15)14(7)11)8-5-3-2-4-6-8/h2-6H,11H2,
    1H3
  • Risk Statements: S61
  • Molecular Formula: C10H10N4O
  • Molecular Structure:CAS No:41394-05-2 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-one

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References of 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5-one
Title: Metamitron
CAS Registry Number: 41394-05-2
CAS Name: 4-Amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one
Manufacturers' Codes: BAY DRW 1139
Trademarks: Goltix (Bayer)
Molecular Formula: C10H10N4O
Molecular Weight: 202.21
Percent Composition: C 59.40%, H 4.98%, N 27.71%, O 7.91%
Literature References: Prepn: K. Dickore et al., DE 2107757; eidem, US 3847914 (1972, 1974 both to Bayer); W. Draber et al., Ann. 1976, 2206. Chemistry and mode of action: idem et al., Proc. 8th Int. Plant Prot. Congress 1, 203 (1975). Comprehensive description: H. Lembrich, Pflanzenschutz-Nachr. 31, 197 (1978). Degradation in soil: R. Allen, A. Walker, Pestic. Sci. 18, 95 (1987). HPLC determn in surface water: R. B. Geerdink, J. Chromatogr. 543, 244 (1991).
Properties: Crystals from isopropanol/water, mp 169°. uv max (methanol): 312 nm (log e 4.06). Vapor pressure (20-70°): <1 ′ 10-4 mbar. Soly (g/100g): water 0.18; isopropanol 0-1; methylene chloride 1-5; toluene 0-1; ligroin (80-110°) 0-1. Stable in acid media; rapidly decomp at pH >10. LD50 orally in male, female rats, male, female mice: 3343, 1832, 1450, 1463 mg/kg; dermally in rats: >500 mg/kg. LC50 (4 hr) in rats, mice, hamsters (mg/m3): >331, >206, >206 by inhalation (Lembrich).
Melting point: mp 169°
Absorption maximum: uv max (methanol): 312 nm (log e 4.06)
Toxicity data: LD50 orally in male, female rats, male, female mice: 3343, 1832, 1450, 1463 mg/kg; dermally in rats: >500 mg/kg; LC50 (4 hr) in rats, mice, hamsters (mg/m3): >331, >206, >206 by inhalation (Lembrich)
Use: Herbicide.