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CAS No 38721-52-7 , Lithium triisobutylhydroborate

  • Name: Lithium triisobutylhydroborate
  • Synonyms: Lithiumbutylborohydride; L-selectride; lithium tri-sec-butylhydroborate;Lithium tri-sec-butylborohydride;Lithium triisobutylhydroborate;
  • CAS Registry Number:
  • Transport: UN 3394
  • Flash Point: -17 ºC
  • Density: 0.89
  • Safety Statements: R11;R14/15;R17;R19;R35
  • Hazard Symbols: C: Corrosive;F: Flammable;
  • Flash Point: -17 ºC
  • EINECS: 254-101-1
  • Molecular Weight: 190.10
  • InChI: InChI=1/3C4H9.B.Li.H/c3*1-3-4-2;;;/h3*3H,4H2,1-2H3;;;/q3*-1;+3;+1;-1
  • Risk Statements: S16;S26;S30;S36/37/39;S45;S7/8
  • Molecular Formula: C12H28BLi
  • Molecular Structure:CAS No:38721-52-7 Lithium triisobutylhydroborate
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38721-52-7 Lithium Tri-sec-Butylborohydride

  • Colorless Liquid 1M in THF In Store 1L/2L/5L/20L/50L/100L/150L/200L stainless steel cylinders
  • China Shanghai Forxine Pharmaceutical Co., Ltd [Manufacturer]
  • Tel: 86-189186-97718
  • Address: 855, Xiangyang Road, Minhang District Shanghai,ShanghaiChina
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38721-52-7 LITHIUM TRI-SEC-BUTYLBOROHYDRIDE, 1M IN THF

  • Germany ABCR GmbH & Co KG [Manufacturer]
  • Tel: +49 721 95061-0
  • Fax: +49 721 95061-80
  • Address: Im Schlehert 10
    76187 Karlsruhe
    Germany ,Germany
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38721-52-7 Lithium Tri-Sec-Butylborohydride

  • China Goly Chemical Co., Ltd. [Manufacturers]
  • Tel: +86-(632)-6163187
  • Fax: +86-(632)-5100028
  • Address: Room No.6.Building21 LongXingBeiLi,ShiZhong, ZaoZhua, ShanDong 277102, ZaoZhuang,ShanDongChina
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38721-52-7 Lithium tri-sec-butylborohydride

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38721-52-7 Lithium tri-sec-butylborohydride

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38721-52-7 Lithium tri-sec-butylborohydride

  • Japan Kanto Chemical Co., Inc. [Manufacturers]
  • Tel: +81 3 3663 7631
  • Fax: +81 3 3667 8277
  • Address: 2-8, Nihonbashi Honcho 3-chome,Chuo-ku, Tokyo, 103-0023, Japan Tokyo,TokyoJapan
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38721-52-7 Lithium tri-sec-butylborohydride

  • China Sinochem Tianjin Co., Ltd. [Manufacturers]
  • Tel: +86-22-23146338
  • Fax: +86-22-23146333
  • Address: 58,Nanjing Road, Tianjin ,China Tianjin,TianjinChina
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38721-52-7 Lithium tri-sec-butylborohydride

  • China Roatak (HK) Enterprise CO., Limited [Distributor/Wholesaler]
  • Tel: 86-10-57191470
  • Fax: 86-10-51413367
  • Address: Room 1007 306#, Shaoyaoju North Block, Chaoyang District, Beijing 100029, China Beijing,BeijingChina
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38721-52-7 Lithium Tri-Sec-Butylborohydride

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38721-52-7 Lithium tri-sec-butylborohydride

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References of Lithium triisobutylhydroborate
Title: Selectride? (Aldrich)
Literature References: Group of stereoselective trialkyl borohydride reducing agents. Reduction of cycloalkenones: J. M. Fortunato, B. Ganem, J. Org. Chem. 41, 2194 (1976). Review of synthetic applications: S. Wittmann, B. Sch?necker, J. Prakt. Chem. Chem.-Ztg. 338, 759-762 (1996).
 
Derivative Type: L-Selectride
CAS Registry Number: 38721-52-7
CAS Name: Lithium (T-4)-hydrotris(1-methylpropyl)borate(1-)
Synonyms: lithium tri-sec-butylborohydride
Molecular Formula: C12H28BLi
Molecular Weight: 190.10
Percent Composition: C 75.82%, H 14.85%, B 5.69%, Li 3.65%
Literature References: Prepn and use in stereoselective reduction of cyclic ketones: H. C. Brown, S. Krishnamurthy, J. Am. Chem. Soc. 94, 7159 (1972). Synthetic use in reduction of cyclic anhydrides: M. A. Makhlouf, B. Rickborn, J. Org. Chem. 46, 4810 (1981); in cleavage of carbamates and O-demethylation of alkaloids: A. Coop et al., ibid. 63, 4392 (1998).
 
Derivative Type: K-Selectride
CAS Registry Number: 54575-49-4
CAS Name: Potassium (T-4)-hydrotris(1-methylpropyl)borate(1-)
Synonyms: potassium tri-sec-butylborohydride
Molecular Formula: C12H28BK
Molecular Weight: 222.26
Percent Composition: C 64.85%, H 12.70%, B 4.86%, K 17.59%
Literature References: Prepn: C. A. Brown, J. Am. Chem. Soc. 95, 4100 (1973); idem, Inorg. Synth. 17, 26 (1977). Synthetic use in conjugate reduction and reductive alkylation of a,b-unsaturated cyclohexenones: B. Ganem, J. Org. Chem. 40, 146 (1975); in reduction of diketo steroids: D. M. Tal et al., Tetrahedron 40, 851 (1984).
Properties: Prepd as a viscous, clear, water-white to yellow soln in THF. Reacts vigorously with water.
 
CAUTION: Solutions in THF may cause skin irritation and chemical burns (C. A. Brown, 1977).
Use: Mild reducing agents in organic synthesis.