Title: Pyridazine
CAS Registry Number: 289-80-5
CAS Name: 1,2-Diazine
Synonyms: orthodiazine; oizine
Molecular Formula: C4H4N2
Molecular Weight: 80.09
Percent Composition: C 59.99%, H 5.03%, N 34.98%
Literature References: Prepd from maleic hydrazide: Mizzoni, Spoerri,
J. Am. Chem. Soc. 73, 1873 (1951). Resonance energy and position of double bonds: Maccoll,
J. Chem. Soc. 1946, 671.
Properties: Liquid. d418 1.107; d423.5 1.1035. mp -8°. bp760 208°; bp14 87°; bp1.0 48°.
nD23.5 1.52311. Dipole moment in dioxane at 35° = 3.94. uv max: 338 nm. Resonance energy: 22 kcal. Miscible with water, benzene, DMF. Freely sol in methanol, ethanol, ether. Practically insol in petr ether.
Melting point: mp -8°
Boiling point: bp760 208°; bp14 87°; bp1.0 48°
Index of refraction: nD23.5 1.52311
Absorption maximum: uv max: 338 nm
Density: d418 1.107; d423.5 1.1035
Derivative Type: Hydrochloride
Molecular Formula: C4H4N2.HCl
Molecular Weight: 116.55
Percent Composition: C 41.22%, H 4.32%, N 24.04%, Cl 30.42%
Properties: Yellow solid, mp 161-163°.
Melting point: mp 161-163°