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CAS No 2104-96-3 , (4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-λ

  • Name: (4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-λ
  • Synonyms: 5-phosphane; Drillzid;Bromofos;(4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-λ Mexion; Nexagan; Bromovur; Nexion; Omexan; Brophene; Brofene;
  • CAS Registry Number:
  • Transport: UN3077 9/PG 3
  • Melting Point: 53-56 °C
  • Flash Point: >100 °C
  • Boiling Point: 140-142 deg C at 0.01 mm Hg
  • Refractive index: 1.582
  • Safety Statements: R22;R50/53
  • Hazard Symbols: Xn: Harmful;N: Dangerous for the environment;
  • Flash Point: >100 °C
  • EINECS: 218-277-3
  • Molecular Weight: 365.996082
  • InchiKey: NYQDCVLCJXRDSK-UHFFFAOYSA-N
  • InChI: InChI=1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,
    1-2H3
  • Risk Statements: S2;S36;S60;S61
  • Molecular Formula: C8H8BrCl2O3PS
  • Molecular Structure:CAS No:2104-96-3 (4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-λ

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References of (4-bromo-2,5-dichlorophenoxy)-dimethoxy-sulfanylidene-λ
Title: Bromophos
CAS Registry Number: 2104-96-3
CAS Name: Phosphorothioic acid O-(4-bromo-2,5-dichlorophenyl) O,O-dimethyl ester
Synonyms: O-(4-bromo-2,5-dichlorophenyl)-O,O-dimethylphosphorothioate; bromophos-methyl
Manufacturers' Codes: ENT-27162; OMS-658; S-1942
Trademarks: Nexion (Boehringer, Ing.)
Molecular Formula: C8H8BrCl2O3PS
Molecular Weight: 366.00
Percent Composition: C 26.25%, H 2.20%, Br 21.83%, Cl 19.37%, O 13.11%, P 8.46%, S 8.76%
Literature References: Prepn: BE 625198 C.A. 60, 13187a (1964); R. Sehring, K. Zeile, US 3227610, US 3275718 (1963, 1966, 1966 all to Boehringer, Ing.). Metabolism in rats: M. Stiasni et al., J. Agric. Food Chem. 15, 474 (1967). Toxicity study: T. B. Gaines, Toxicol. Appl. Pharmacol. 14, 515 (1969). Review: D. Eichler, Residue Rev. 41, 65-112 (1972).
Properties: Yellow crystals, mp 53-54°. bp0.01 140-142°. Vapor pressure at 20°C: 1.3 ′ 10-4 mm Hg. Soly in water at 25°: 40 mg/l. Sol in CCl4, ether, toluene. Stable in soln up to pH 9. Non-corrosive. LD50 in male, female rats (mg/kg): 1600, 1730 orally (Gaines).
Melting point: mp 53-54°
Boiling point: bp0.01 140-142°
Toxicity data: LD50 in male, female rats (mg/kg): 1600, 1730 orally (Gaines)
 
Derivative Type: O,O-Diethyl analog
Synonyms: Bromophos-ethyl
Manufacturers' Codes: ENT-27258; OMS-659; S-2225
Trademarks: Nexagan (Boehringer, Ing.)
Molecular Formula: C10H12BrCl2O3PS
Molecular Weight: 394.05
Percent Composition: C 30.48%, H 3.07%, Br 20.28%, Cl 17.99%, O 12.18%, P 7.86%, S 8.14%
Properties: Colorless to pale yellow oil, bp0.001 122-133°. Vapor pressure at 30°: 4.6 ′ 10-5 mm Hg. Soly in water at 25°: 2 mg/l.
Boiling point: bp0.001 122-133°
 
Use: Insecticide, acaricide.