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CAS No 14523-22-9 , carbonyl dichloride

  • Name: carbonyl dichloride
  • Synonyms: CTK4C4438;14523-22-9; Rhodium,tetracarbonyldi-m-chlorodi-;rhodium; ACMC-1C44N;carbonyl dichloride;
  • CAS Registry Number:
  • Transport: UN3466
  • Melting Point: 120-125 °C (dec.)(lit.)
  • Flash Point: °C
  • Boiling Point: °Cat760mmHg
  • Density: g/cm3
  • Safety Statements: R25:Toxicifswallowed.;R36/38:Irritatingtoeyesandskin.;
  • Hazard Symbols: T:Toxic;
  • Flash Point: °C
  • EINECS: 238-540-6
  • Molecular Weight: 201.8216
  • InchiKey: ADGFUTSPEKVFKD-UHFFFAOYSA-N
  • InChI: InChI=1S/CCl2O.Rh/c2-1(3)4;
  • Risk Statements: S15:Keepawayfromheat.;S26:Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedicaladvice.;S28A:Aftercontactwithskin,washimmediatelywithplentyofwater.;S37/39:Wearsuitableglovesandeye/faceprotection.;
  • Molecular Formula: CCl2ORh
  • Molecular Structure:CAS No:14523-22-9 carbonyl dichloride

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References of carbonyl dichloride
Title: Rhodium Carbonyl Chloride
CAS Registry Number: 14523-22-9
CAS Name: Tetracarbonyldi-m-chlorodirhodium
Synonyms: dichlorotetracarbonyldirhodium; chlorodicarbonylrhodium(I) dimer
Molecular Formula: C4Cl2O4Rh2
Molecular Weight: 388.76
Percent Composition: C 12.36%, Cl 18.24%, O 16.46%, Rh 52.94%
Line Formula: [Rh(CO)2Cl]2
Literature References: Prepn: Hieber, Lagally, Z. Anorg. Allg. Chem. 251, 96 (1943); McCleverty, Wilkinson, Inorg. Synth. 8, 211 (1966); Colton et al., Aust. J. Chem. 23, 1351 (1970); Cramer, Inorg. Synth. 15, 14 (1974). Structure: Dahl et al., J. Am. Chem. Soc. 83, 1761 (1961).
Properties: Orange-red crystalline solid or red crystalline sublimate. mp 124-125°. Sol in most organic solvents (except aliphatic hydrocarbons). Stable to dry air. Solutions in organic solvents decompose when exposed to air.
Melting point: mp 124-125°
Use: Catalyst.