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CAS No 12772-57-5 , Radicicol

  • Name: Radicicol
  • Synonyms: Monorden A;Radicicol; b-Resorcylic acid,5-chloro-6-(7,8-epoxy-10-hydroxy-2-oxo-3,5-undecadienyl)-, m-lactone (7CI); NSC 294404; Radicicol R 2146;Monorden; Monordene; Radicolol;Radicicol(8CI); (+)-Monorden A;Radisicol;
  • CAS Registry Number:
  • Transport: UN 2811 6.1/PG 3
  • Density: 1.364 g/cm3
  • Refractive index: 1.583
  • Water Solubility: ethanol: 10 mg/mL ,Soluble in DMSO (20 mg/ml-clear colorless solution)
  • Safety Statements: 26
  • Hazard Symbols: Xn: Harmful;
  • Molecular Weight: 364.78
  • InChI: InChI=1S/C18H17ClO6/c1-9-6-15-14(25-15)5-3-2-4-10(20)7-11-16(18(23)24-9)12(21)8-13(22)17(11)19/h2-5,8-9,14-15,21-22H,6-7H2,1H3/b4-2+,5-3+
  • Risk Statements: 22-36/37/38
  • Molecular Formula: C18H17ClO6
  • Molecular Structure:CAS No:12772-57-5 Radicicol

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12772-57-5 RADICICOL

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12772-57-5 6H-Oxireno[e][2]benzoxacyclotetradecin-6,12(7H)-dione,8-chloro-1a,14,15,15a-tetrahydro-9,11-dihydroxy-14-methyl-,(1aR,2Z,4E,14R,15aR)-

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References of Radicicol
Title: Monorden
CAS Registry Number: 12772-57-5
CAS Name: 8-Chloro-1a,14,15,15a-tetrahydro-9,11-dihydroxy-14-methyl-6H-oxireno[e][2]benzoxacyclotetradecin-6,12(7H)-dione
Synonyms: 5-chloro-6-(7,8-epoxy-10-hydroxy-2-oxo-3,5-undecadienyl)-b-resorcylic acid m-lactone; radicicol
Molecular Formula: C18H17ClO6
Molecular Weight: 364.78
Percent Composition: C 59.27%, H 4.70%, Cl 9.72%, O 26.32%
Literature References: Antibiotic substance from Monosporium bonorden: Delmotte, Delmotte-Plaquée, Nature 171, 344 (1953). Identity with radicicol: Mirrington et al., Tetrahedron Lett. 1964, 365. Structure: McCapra, Scott, ibid. 1964, 869; Mirrington et al., Aust. J. Chem. 19, 1265 (1966). Isoln: NL 6506173 (1965 to Sandoz).
Properties: Crystals from chloroform, alcohol or benzene, mp 193.5°. [a]D20 +203° (chloroform). uv max (ethanol): 264, 272 nm (e 13200, 13100).
Melting point: mp 193.5°
Optical Rotation: [a]D20 +203° (chloroform)
Absorption maximum: uv max (ethanol): 264, 272 nm (e 13200, 13100)
 
Derivative Type: Diacetate
Molecular Formula: C22H21ClO8
Molecular Weight: 448.85
Percent Composition: C 58.87%, H 4.72%, Cl 7.90%, O 28.52%
Properties: Crystals, mp 189°. uv max: 275 nm (e 13000).
Melting point: mp 189°
Absorption maximum: uv max: 275 nm (e 13000)