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CAS No 78948-87-5 , Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-kOO,kO']-, hydrogen (1:2), (T-4)-

  • Name: Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-kOO,kO']-, hydrogen (1:2), (T-4)-
  • Synonyms: Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-kOO,kO']-, hydrogen (1:2), (T-4)-;Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-O1,OO1]-, dihydrogen, (T-4)-;Magnesate(2-), bis[2-carboxybenzenecarboperoxoato(2-)-kO,kOO]-, dihydrogen, (T-4)- (9CI); H 48 (bleaching agent); Interox H48; Magnesium monoperoxyphthalate; H 48; Benzenecarboperoxoicacid, 2-carboxy-, magnesium complex; MMPP;
  • CAS Registry Number:
  • Transport: 1479
  • Melting Point: 93°C (dec.)
  • Safety Statements: Risk Statements 8-36/37/38Safety Statements 17-26-27-36/37/39RIDADR 1479
  • EINECS: 279-013-0
  • Molecular Weight: 492.6254
  • InChI: InChI=1/C8H6O5.Mg.6H2O/c9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h1-4,12H,(H,9,10);;6*1H2/q;+2;;;;;;/p-2
  • Risk Statements: 8-36/37/38
  • Molecular Formula: C16H20MgO16-2
  • Molecular Structure:CAS No:78948-87-5 Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-kOO,kO']-, hydrogen (1:2), (T-4)-

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References of Magnesate(2-),bis[2-carboxybenzenecarboperoxoato(2-)-kOO,kO']-, hydrogen (1:2), (T-4)-
Title: Magnesium Monoperoxyphthalate
CAS Registry Number: 78948-87-5
CAS Name: (T-4)-Bis[2-carboxybenzenecarboperoxoato(2-)-kO,kOO]magnesate(2-) dihydrogen
Synonyms: magnesium bis(monoperoxyphthalate); H48; MMPP
Molecular Formula: C16H10MgO10
Molecular Weight: 386.55
Percent Composition: C 49.71%, H 2.61%, Mg 6.29%, O 41.39%
Literature References: Versatile, mild peroxygen product; stable alternative to m-chloroperoxybenzoic acid (MCPBA) in oxidation reactions. Prepn: G. J. Hignett, EP 27693; idem, US 4385008 (1981, 1983 both to Interox). Thermal decompn studies: B. M. Kariuki, W. Jones, Mol. Cryst. Liq. Cryst. 186, 45 (1990); eidem, ibid. 248, 21 (1994). Decontamination reactions with warfare agents and insecticides: C. Lion et al., Phosphorus Sulfur Silicon Relat. Elem. 56, 213 (1991). Antimicrobial properties: M. G. C. Baldry, J. Appl. Bacteriol. 57, 499 (1984). Clinical evaluation as an anti-plaque mouthrinse and dentifrice: C. Scully et al., J. Clin. Periodontol. 26, 234 (1999). Review of synthetic applications in oxidation reactions: P. Brougham et al., Synthesis 1987, 1015-1017; H. Heaney, Aldrichim. Acta 26, 35-45 (1993).
 
Derivative Type: Hexahydrate
CAS Registry Number: 131391-55-4
Molecular Formula: C16H10MgO10.6H2O
Molecular Weight: 494.64
Percent Composition: C 38.85%, H 4.48%, Mg 4.91%, O 51.75%
Properties: White granular solid, mp 96°. Soly in water (15°): 160 g/l. Sol in low mol wt alcohols; very low soly in common organic solvents.
Melting point: mp 96°
 
Use: Oxidizing agent in organic synthesis. Bleaching agent. Decontaminant reagent for nerve gases and insecticides.