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CAS No 5815-08-7 , N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine

  • Name: N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine
  • Synonyms: BREDERECK REAGENT;5815-08-7;N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine; 1-tert-butoxy-n,n,n',n'-tetramethylmethanediamine; tert-Butoxy bis(dimethylamino)methane;
  • CAS Registry Number:
  • Transport: UN 1993
  • Flash Point: 41 ºC
  • Boiling Point: 50-55 ºC
  • Density: 0.844
  • Refractive index: 1.422
  • Safety Statements: R10;R36/37/38
  • Hazard Symbols: Xi: Irritant;
  • Flash Point: 41 ºC
  • EINECS: 227-383-9
  • Molecular Weight: 174.28378
  • InchiKey: HXRAMSFGUAOAJR-UHFFFAOYSA-N
  • InChI: InChI=1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
  • Risk Statements: S26
  • Molecular Formula: C9H22N2O
  • Molecular Structure:CAS No:5815-08-7 N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine
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5815-08-7 N,N-dimethylformamide di-tert-butyl acetal

  • N,N-dimethylformamide di-tert-butyl acetal, 98%
  • China Shaanxi Hookin Pharma & Chemical Co., Ltd. [Manufacturers]
  • Tel: 86 29 8834 8841 / +86 29 8703 6202
  • Fax: 86-29-88348843 87036201
  • Address: No.3,Nanwei 7th Road,Yangling Industry Zone,Shaanxi,PR.China. xi'an,shanxiChina
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5815-08-7 Bredereck reagent, min. 90%

  • Bredereck reagent, min. 90%
  • Poland BUJNO Synthesis Sp. z o.o. [Manufacturer]
  • Tel: +48 22 606 36 95
  • Fax: +48 22 606 36 99
  • Address: Rakowiecka 36 02-532 WarsawPoland Warsaw,nullPoland
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5815-08-7 tert-butoxy-bis(dimethylamino)methane

  • India Globe Chemie [Manufacturers]
  • Tel: +91-20-32309500
  • Fax: +91-20-22952576
  • Address: 3,Chandraneel Apt.,Near DSK Raanwara, Bavdhan Pune,MaharashtraIndia
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5815-08-7 tert-Butoxy-bis(dimethylamino)methane; 98%

  • tert-Butoxy-bis(dimethylamino)methane; 98%
  • Germany ABCR GmbH & Co KG [Manufacturer]
  • Tel: +49 721 95061-0
  • Fax: +49 721 95061-80
  • Address: Im Schlehert 10
    76187 Karlsruhe
    Germany null,nullGermany
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5815-08-7 N,N-Dimethylformamide dibutylacetal

  • N,N-Dimethylformamide dibutylacetal
  • Germany CHEMOS GmbH [Manufacturer]
  • Tel: 0049 9402/9336 0
  • Fax: 0049 9402/9336 13
  • Address: CHEMOS GmbH
    Werner-von-Siemensstr. 3
    93128 Regenstauf
    Germany null,nullGermany
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5815-08-7 N,N-DIMETHYLFORMAMIDE DI-TERT-BUTYL ACETAL [FOR ESTERIFICATION]

  • N,N-DIMETHYLFORMAMIDE DI-TERT-BUTYL ACETAL [FOR ESTERIFICATION]
  • Hong kong Advanced Technology & Industrial Co., Ltd. [Manufacturer]
  • Tel: (852) 2390 2293/ (852) 2394 5546
  • Fax: (852) 2789 8314
  • Address: Unit B, 1/F., Cheong Shing Bldg.,
    17 Walnut St., Tai Kok Tsui, Kln,
    Hong Kong null,nullHong kong
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References of N,N,N',N'-tetramethyl-1-[(2-methylpropan-2-yl)oxy]methanediamine
Title: Bredereck's Reagent
CAS Registry Number: 5815-08-7
CAS Name: 1-(1,1-Dimethylethoxy)-N,N,N¢,N¢-tetramethylmethanediamine
Synonyms: bis(dimethylamino)-tert-butyloxymethane; tert-butoxybis(dimethylamino)methane; tert-butoxy-N,N,N¢,N¢-tetramethylmethanediamine
Molecular Formula: C9H22N2O
Molecular Weight: 174.28
Percent Composition: C 62.02%, H 12.72%, N 16.07%, O 9.18%
Literature References: Aminal ester used in condensation reactions. Prepn: H. Bredereck et al., Angew. Chem. Int. Ed. 6, 356 (1967); idem et al., Ber. 101, 41 (1968). Synthetic applications: B. M. Trost, M. Preckel, J. Am. Chem. Soc. 95, 7862 (1973); W. Haefliger, H. Knecht, Tetrahedron Lett. 25, 285 (1983); J.-P. Vors, J. Heterocycl. Chem. 28, 1043 (1991); A. C. Spivey et al., J. Org. Chem. 65, 5253 (2000); E. Morera et al., Org. Lett. 4, 1139 (2002); S. Csihony et al., Adv. Synth. Catal. 346, 1081 (2004). Review: W. Kantlehner, J. Prakt. Chem. Chem.-Ztg. 337, 418-421 (1995).
Properties: bp10-12 48-52°. bp15 50-55°. nD20 1.4260.
Boiling point: bp10-12 48-52°; bp15 50-55°
Index of refraction: nD20 1.4260
Use: Mild enamination reagent; catalyst in ring-opening polymerization reactions.