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CAS No 56-73-5 , [(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl dihydrogen phosphate Search by region : China

  • Name: [(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl dihydrogen phosphate
  • Synonyms: Glucose 6-(dihydrogen phosphate); D-Glucose 6-phosphate;Robison ester; 6-O-phosphono-D-glucopyranose;[(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl dihydrogen phosphate; glucose-6-phosphate; Glucose 6-phosphate;
  • CAS Registry Number:
  • Transport: UN 1760 8/PG 2
  • Flash Point: 295°C
  • Boiling Point: 564.1°C at 760 mmHg
  • Density: 1.97g/cm3
  • Refractive index: 1.637
  • Safety Statements: Mutation data reported. When heated to decomposition it emits toxic vapors of POx.
  • Hazard Symbols: C
  • Flash Point: 295°C
  • EINECS: 200-286-9
  • Molecular Weight: 260.135782
  • InchiKey: NBSCHQHZLSJFNQ-GASJEMHNSA-N
  • InChI: InChI=1S/C6H13O9P/c7-3-2(1-14-16(11,12)13)15-6(10)5(9)4(3)8/h2-10H,1H2,
    (H2,11,12,13)/t2-,3-,4+,5-,6?/m1/s1
  • Risk Statements: 34
  • Molecular Formula: C6H13O9P
  • Molecular Structure:CAS No:56-73-5 [(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl dihydrogen phosphate

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References of [(2R,3S,4S,5R)-3,4,5,6-tetrahydroxyoxan-2-yl]methyl dihydrogen phosphate
Title: Glucose-6-phosphate
CAS Registry Number: 56-73-5
CAS Name: D-Glucose 6-(dihydrogen phosphate)
Synonyms: glucose-6-phosphoric acid; Robison ester
Molecular Formula: C6H13O9P
Molecular Weight: 260.14
Percent Composition: C 27.70%, H 5.04%, O 55.35%, P 11.91%
Literature References: A normal constituent of resting muscle, probably always existing in equilibrium with fructose-6-phosphate. For the enzymatic conversion from the 1-phosphate see a-Glucose-1-phosphate. Isoln from a crude mixture of hexose phosphates, obtained by yeast fermentation: Robison, King, Biochem. J. 25, 323 (1931). Prepn by the action of phosphoglucomutase on a-glucose-1-phosphate: Colowick, Sutherland, J. Biol. Chem. 144, 423 (1942); from acetone glucose: Levene, Raymond, ibid. 92, 757 (1931); by phosphorylation of 1,2,3,4-tetraacetylglucose followed by deacetylation: Fischer, Lardy, ibid. 164, 513 (1946); Biochem. Prep. 2, 39 (1952). Prepn from starch: de Chatelperron et al., FR 1379068 (1964), C.A. 62, 9394b (1965).
 
Derivative Type: Barium salt
Molecular Formula: C6H11O5PO4Ba
Molecular Weight: 395.45
Percent Composition: C 18.22%, H 2.80%, O 36.41%, P 7.83%, Ba 34.73%
Properties: Nonhygroscopic, stable powder. [a]D24 +17.9°. Easily sol in water.
Optical Rotation: [a]D24 +17.9°
 
Derivative Type: Dipotassium salt
Molecular Formula: C6H11O5PO4K2
Molecular Weight: 336.32
Percent Composition: C 21.43%, H 3.30%, O 42.81%, P 9.21%, K 23.25%
Properties: Precipitate from methanol. [a]D24 +21.2° (c = 1.3). Freely sol in water.
Optical Rotation: [a]D24 +21.2° (c = 1.3)