Home > Name List By b > Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI)

CAS No 521-85-7 , Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI)

  • Name: Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI)
  • Synonyms: (+)-Corycavine;Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI);Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (R)- (8CI); Corycavamine;
  • CAS Registry Number:
  • Flash Point: 277.1°C
  • Boiling Point: 534.6°Cat760mmHg
  • Density: 1.28g/cm3
  • Refractive index: 1.596
  • Flash Point: 277.1°C
  • Molecular Weight: 367.4
  • InChI: InChI=1/C21H21NO5/c1-12-14-3-4-17-21(27-11-24-17)16(14)9-22(2)6-5-13-7-18-19(26-10-25-18)8-15(13)20(12)23/h3-4,7-8,12H,5-6,9-11H2,1-2H3/t12-/m1/s1
  • Molecular Formula: C21H21 N O5
  • Molecular Structure:CAS No:521-85-7 Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI)

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521-85-7 CORYCAVINE(P)

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References of Bis[1,3]benzodioxolo[4,5-c:5',6'-g]azecin-13(5H)-one,4,6,7,14-tetrahydro-5,14-dimethyl-, (14R)- (9CI)
Title: Corycavamine
CAS Registry Number: 521-85-7
CAS Name: (14R)-4,6,7,14-Tetrahydro-5,14-dimethylbis[1,3]benzodioxolo[4,5-c:5￠,6￠-g]azecin-13(5H)-one
Synonyms: 7,13-dimethyl-2,3:9,10-bis(methylenedioxy)-7,13a-secoberbin-13a-one
Molecular Formula: C21H21NO5
Molecular Weight: 367.40
Percent Composition: C 68.65%, H 5.76%, N 3.81%, O 21.77%
Literature References: In Corydalis cava (L.) Schweigg & Korte (C. tuberosa DC.), Fumariaceae: Gadamer et al., Arch. Pharm. 240, 81 (1902). Structure: von Bruchhausen, ibid. 263, 570 (1925). Corycavamine and corycavine originally depicted as the keto and enol tautomers, resp.
Properties: Rhombic columns from ether and alcohol, mp 149°. Is converted to corycavine at the mp. [a]D20 +167° (chloroform). Sol in alcohol and chloroform.
Melting point: mp 149°
Optical Rotation: [a]D20 +167° (chloroform)
 
Derivative Type: dl-Form
Synonyms: Corycavine
Properties: Orthorhombic plates from alc, mp 218°, mp 222° in vac. Very slightly sol in water; sol in abs alcohol and chloroform; unstable to light.
Melting point: mp 218°; mp 222° in vac
 
 
Status: This monograph has been retired and is no longer subject to revision or update.