References of 4-methoxy-9-methyl-6,7,8,9-tetrahydro-[1,3]dioxolo[4,5-h]isoquinoline
Title: Anhalonine
CAS Registry Number: 519-04-0
CAS Name: 6,7,8,9-Tetrahydro-4-methoxy-9-methyl-1,3-dioxolo[4,5-
h]isoquinoline
Molecular Formula: C12H15NO3
Molecular Weight: 221.25
Percent Composition: C 65.14%, H 6.83%, N 6.33%, O 21.69%
Literature References: From mescal buttons
[Lophophora williamsii (Lemaire) Coult. (
Anhalonium lewinii Henn.),
Cactaceae] also in
Ariocarpus, in
Gymnocalycium gibbosum. Synthesis of
dl-form and resolution: Sp?th, Kesztler,
Ber. 68, 1663 (1935); Brossi
et al., J. Am. Chem. Soc. 93, 6248 (1971). Configuration: Battersby, Edwards,
J. Chem. Soc. 1960, 1214.
Properties: Rhombic needles from petr ether, mp 86°, bp0.02 140°. [a]D25 -63.8° (methanol); -56.3° (chloroform). Very sol in alcohol, ether, chloroform, benzene, petr ether.
Melting point: mp 86°
Boiling point: bp0.02 140°
Optical Rotation: [a]D25 -63.8° (methanol); -56.3° (chloroform)
Derivative Type: Hydrochloride
Molecular Formula: C12H15NO3.HCl
Molecular Weight: 257.71
Percent Composition: C 55.93%, H 6.26%, N 5.44%, O 18.62%, Cl 13.76%
Properties: Orthorhombic prisms, dec 255°; freely sol in hot water. Aq soln is neutral.