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CAS No 493-52-7 , 2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid

  • Name: 2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid
  • Synonyms: 493-52-7; 4-Dimethylamino-2'-carboxylazobenzene;2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid; Acid Red 2;O-METHYL RED; C.I. Acid Red 2; 2-Carboxy-4'-(dimethylamino)azobenzene;
  • CAS Registry Number:
  • Transport: UN 1170
  • Melting Point: 178-182 ºC
  • Boiling Point: 479.5°Cat760mmHg
  • Density: 0.839 g/mL at 25 °C
  • Refractive index: 1.592
  • Safety Statements: R10;R20/21/22;R68
  • Hazard Symbols: Xn: Harmful;
  • HS Code: 29270000
  • EINECS: 207-776-1
  • Molecular Weight: 269.2985
  • InchiKey: CEQFOVLGLXCDCX-UHFFFAOYSA-N
  • InChI: InChI=1S/C15H15N3O2/c1-18(2)12-9-7-11(8-10-12)16-17-14-6-4-3-5-13(14)15
    (19)20/h3-10H,1-2H3,(H,19,20)
  • Risk Statements: S36/37
  • Molecular Formula: C15H15N3O2
  • Molecular Structure:CAS No:493-52-7 2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid

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493-52-7 Methyl Red, Neutral

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493-52-7 4-DIMETHYLAMINOAZOBENZENE-2''-CARBOXYLIC ACID

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493-52-7 METHYL RED, NEUTRAL, REAGENT

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References of 2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid
Title: Methyl Red
CAS Registry Number: 493-52-7
CAS Name: 2-[[4-(Dimethylamino)phenyl]azo]benzoic acid
Synonyms: C.I. Acid Red 2; C.I. 13020
Molecular Formula: C15H15N3O2
Molecular Weight: 269.30
Percent Composition: C 66.90%, H 5.61%, N 15.60%, O 11.88%
Literature References: Prepn by diazotization of anthranilic acid and coupling with dimethylaniline: Clarke, Kirner, Org. Synth. 2, 47 (1922). See also Colour Index vol. 4 (3rd ed., 1971) p 4043.
Properties: Glistening, violet crystals from toluene. mp 181-182°. pKa1 2.5; pKa2 9.5; pKb 4.8. Almost insol in water; sol in alcohol and in acetic acid.
Melting point: mp 181-182°
pKa: pKa1 2.5; pKa2 9.5; pKb 4.8
Use: As indicator in 0.1% alcoholic soln; pH: 4.4 red, 6.2 yellow. Used for titrating NH3, weak organic bases, e.g., alkaloids; not suitable for organic acids, except oxalic and picric acid. Methyl red is easily reduced, thereby losing its color, and readings should be made promptly. It is gradually being replaced by sulfonphthalein indicators, such as bromcresol green, which are more stable and exhibit a sharper change in color.