References of (2S,3R,4S,5S,6R)-2-[4-[(3R,3aR,6S,6aR)-3-(3,4-dimethoxyphenyl)-1,3,3a,4,
6,6a-hexahydrofuro[3,
4-c]furan-6-yl]-2-methoxyphenoxy]-6-(hydroxymethyl)oxane-3,4,5-triol
Title: Phillyrin
CAS Registry Number: 487-41-2
CAS Name: [1
S-(1a,3aa,4b,6aa)]-4-[4-(3,4-Dimethoxyphenyl)tetrahydro-1
H,3
H-furo[3,4-
c]furan-1-yl]-2-methoxyphenyl-b-D-glucopyranoside
Synonyms: phyllyrin; phillyroside; forsythin
Molecular Formula: C27H34O11
Molecular Weight: 534.55
Percent Composition: C 60.67%, H 6.41%, O 32.92%
Literature References: From bark of
Phillyrea latifolia L., and allied
Oleaceae: Campona,
Ann. 24, 242 (1837); Eijkman,
Rec. Trav. Chim. 5, 127 (1886); Kramer,
Compt. Rend. 196, 814 (1933); Sosa,
Bull. Soc. Chim. Biol. 29, 918 (1947). Structure: Kaku
et al., J. Pharm. Soc. Jpn. 59, 248 (1939); M. Chiba
et al., Chem. Pharm. Bull. 25, 3435 (1977).
Derivative Type: a-Form
Properties: Needles from dil alc, mp 154-155°. [a]D +48.4° (alcohol).
Melting point: mp 154-155°
Optical Rotation: [a]D +48.4° (alcohol)
Derivative Type: b-Form
Properties: Needles, mp 184-185°. [a]D +48.5° (alcohol).
Melting point: mp 184-185°
Optical Rotation: [a]D +48.5° (alcohol)