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CAS No 485-64-3 , Cinchonan-9-ol,10,11-dihydro-, (8a,9R)-

  • Name: Cinchonan-9-ol,10,11-dihydro-, (8a,9R)-
  • Synonyms: Cinchamidine; Dihydrocinchonidine;Cinchonan-9-ol,10,11-dihydro-, (8a,9R)-; (-)-Dihydrocinchonidine;Hydrocinchonidine(6CI,7CI,8CI); (-)-Hydrocinchonidine;10,11-Dihydrocinchonidine;
  • CAS Registry Number:
  • Flash Point: 236.3°C
  • Boiling Point: 467.1°Cat760mmHg
  • Density: 1.18g/cm3
  • Refractive index: 1.638
  • Flash Point: 236.3°C
  • EINECS: 207-620-2
  • Molecular Weight: 296.40666
  • InChI: InChI=1/C19H24N2O/c1-2-13-12-21-10-8-14(13)11-18(21)19(22)16-7-9-20-17-6-4-3-5-15(16)17/h3-7,9,13-14,18-19,22H,2,8,10-12H2,1H3/t13-,14-,18-,19+/m0/s1
  • Molecular Formula: C19H24 N2 O
  • Molecular Structure:CAS No:485-64-3 Cinchonan-9-ol,10,11-dihydro-, (8a,9R)-

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References of Cinchonan-9-ol,10,11-dihydro-, (8a,9R)-
Title: Hydrocinchonidine
CAS Registry Number: 485-64-3
CAS Name: (8a,9R)-10,11-Dihydrocinchonan-9-ol
Synonyms: (-)-dihydrocinchonidine; cinchamidine
Molecular Formula: C19H24N2O
Molecular Weight: 296.41
Percent Composition: C 76.99%, H 8.16%, N 9.45%, O 5.40%
Literature References: Found in cinchona barks: Forst, B?hringer, Ber. 14, 1270 (1881); Hesse, ibid. 1683; idem, Ann. 214, 1 (1882); Skita, Nord, Ber. 45, 3312 (1912); Heidelberger, Jacobs, J. Am. Chem. Soc. 41, 817 (1919). Configuration: Ochiai et al., J. Pharm. Soc. Jpn. 67, 211 (1947). Stereospecific synthesis from secologanin: R. T. Brown, D. Curless, Tetrahedron Lett. 27, 6005 (1986). Total synthesis: M. Ihara et al., J. Chem. Soc. Perkin Trans. 1 1988, 1277. Stereoisomer of hydrocinchonine, q.v.
Properties: Needles or leaflets, mp 230°. [a]D15 -98° (alcohol). Practically insol in water. Sol in alcohol, chloroform; slightly sol in ether.
Melting point: mp 230°
Optical Rotation: [a]D15 -98° (alcohol)