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CAS No 41198-08-7 , 4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene

  • Name: 4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene
  • Synonyms: Caswell No. 266AA; (+)-Profenofos;4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene; Polycron; CGA 15324; 41198-08-7; (-)-Profenofos;Curacron; Selecron;
  • CAS Registry Number:
  • Transport: 3018
  • Flash Point: 197
  • Boiling Point: 110 ºC (0.001 TORR)
  • Density: 1.482g/cm3
  • Refractive index: 1.5466 (20 C)
  • Safety Statements: Poison by ingestion and skin contact. When heated to decomposition it emits very toxic SOx, POx, Br−, and Cl−. See also ESTERS.
  • Hazard Symbols: Xn,N,T
  • Flash Point: 197
  • EINECS: 255-255-2
  • Molecular Weight: 373.630762
  • InchiKey: QYMMJNLHFKGANY-UHFFFAOYSA-N
  • InChI: InChI=1S/C11H15BrClO3PS/c1-3-7-18-17(14,
    15-4-2)16-11-6-5-9(12)8-10(11)13/h5-6,8H,3-4,7H2,1-2H3
  • Risk Statements: 20/21/22-50/53-24-20/22
  • Molecular Formula: C11H15BrClO3PS
  • Molecular Structure:CAS No:41198-08-7 4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene

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References of 4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene
Title: Profenofos
CAS Registry Number: 41198-08-7
CAS Name: O-(4-Bromo-2-chlorophenyl)phosphorothioic acid O-ethyl S-propyl ester
Manufacturers' Codes: CGA-15324; OMS-2004
Trademarks: Curacron (Syngenta); Sanofos (Sanonda); Selecron (Syngenta)
Molecular Formula: C11H15BrClO3PS
Molecular Weight: 373.63
Percent Composition: C 35.36%, H 4.05%, Br 21.39%, Cl 9.49%, O 12.85%, P 8.29%, S 8.58%
Literature References: Organophosphorus insecticide for use in cotton and vegetables. Prepn: E. Beriger, J. Drabek, BE 789937; eidem, US 3992533 (1973, 1976 both to Ciba-Geigy). Resolution and biological activity of chiral isomers: H. Leader, J. E. Casida, J. Agric. Food Chem. 30, 546 (1982). Persistence and biochemical effects of residue in potatoes: R. A. Habiba et al., ibid. 40, 1852 (1992); in tomatoes: S. M. M. Ismail et al., ibid. 41, 610 (1993). Effect on microbial flora of soil: A. Y. Abdel-Mallek et al., Microbiol. Res. 149, 167 (1994). Toxicity to eastern rainbow fish: A Kumar, J. C. Chapman, Environ. Toxicol. Chem. 17, 1799 (1998). Review of physical properties and field trials: F. Buholzer, Proc. 8th Br. Insectic. Fungic. Conf. 1975, 659-665.
Properties: Slightly yellowish liquid. bp0.001 110°. d20 1.455 g/cc. Soly in water at 20°: 20 ppm. Misc with methanol, dichloromethane, benzene, hexane. Vapor pressure at 20°: ~10-5 mm Hg. n20D 1.5466. LD50 in rat (mg/kg): 358-400 orally; ~3300 dermally; LC50 (4 hr) in rat (mg/m3): ~3000 by inhalation (Buholzer). LC50 (96 hr) in rainbow fish: 0.91 mg/l (Kumar, Chapman).
Boiling point: bp0.001 110°
Index of refraction: n20D 1.5466
Density: d20 1.455
Toxicity data: LD50 in rat (mg/kg): 358-400 orally; ~3300 dermally; LC50 (4 hr) in rat (mg/m3): ~3000 by inhalation (Buholzer); LC50 (96 hr) in rainbow fish: 0.91 mg/l (Kumar, Chapman).
Use: Insecticide; acaricide.