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CAS No 36635-61-7 , 1-(isocyanomethylsulfonyl)-4-methylbenzene

  • Name: 1-(isocyanomethylsulfonyl)-4-methylbenzene
  • Synonyms: 4-Tolylsulfonylmethyl isocyanide;Tosylmethyl isocyanide; (p-Tolylsulfonyl)methyl isocyanide; p-Toluenesulfonylmethyl isocyanide;1-(isocyanomethylsulfonyl)-4-methylbenzene; 36635-61-7; TosMIC;
  • CAS Registry Number:
  • Transport: UN 2811
  • Melting Point: 110-115 ºC
  • Density: 1.24 g/cm3
  • Safety Statements: R23/24/25
  • Hazard Symbols: T: Toxic;
  • HS Code: 29299000
  • EINECS: 253-140-1
  • Molecular Weight: 195.23826
  • InchiKey: CFOAUYCPAUGDFF-UHFFFAOYSA-N
  • InChI: InChI=1S/C9H9NO2S/c1-8-3-5-9(6-4-8)13(11,12)7-10-2/h3-6H,7H2,1H3
  • Risk Statements: S28A;S36/37/39;S38;S45
  • Molecular Formula: C9H9NO2S
  • Molecular Structure:CAS No:36635-61-7 1-(isocyanomethylsulfonyl)-4-methylbenzene

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References of 1-(isocyanomethylsulfonyl)-4-methylbenzene
Title: Tosylmethyl Isocyanide
CAS Registry Number: 36635-61-7
CAS Name: 1-[(Isocyanomethyl)sulfonyl]-4-methylbenzene
Synonyms: (4-methylphenylsulfonyl)methyl isocyanide; p-toluenesulfonylmethyl isocyanide; TosMIC
Molecular Formula: C9H9NO2S
Molecular Weight: 195.24
Percent Composition: C 55.37%, H 4.65%, N 7.17%, O 16.39%, S 16.42%
Literature References: Isonitrile reagent with reversed polarity; serves as a carbonyl anion equivalent in organic synthesis. Prepn: U. Sch?llkopf et al., Ann. 766, 130 (1972); A. M. van Leusen et al., Tetrahedron Lett. 13, 2367 (1972); B. E. Hoogenboom et al., Org. Synth. 57, 102 (1977). Review of applications in organic synthesis: C. Lamberth, J. Prakt. Chem. Chem.-Ztg. 340, 483-485 (1998); V. K. Tandon, S. Rai, Sulfur Rep. 24, 307-385 (2003).
Properties: Crystals from methanol, mp 116-117° (dec).
Melting point: mp 116-117°
Use: Versatile synthon in organic chemistry, esp in the synthesis of heterocyclic compds.