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CAS No 18791-21-4 , Pyridomycin

  • Name: Pyridomycin
  • Synonyms: Pyridomycin;3-Hydroxy-N-[(2Z,5R,6S,9S,10S,11R)-10-hydroxy-5,11-dimethyl-2-(1-methylpropylidene)-3,7,12-trioxo-9-(3-pyridylmethyl)-1,4-dioxa-8-azacyclododeca-6-yl]-2-pyridinecarboxamide;
  • CAS Registry Number:
  • Density: 1.35g/cm3
  • Refractive index: 1.606
  • Safety Statements: Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NOx.
  • Molecular Weight: 0
  • InChI: InChI=1/C27H32N4O8/c1-5-14(2)23-27(37)38-16(4)20(31-25(35)21-19(32)9-7-11-29-21)24(34)30-18(12-17-8-6-10-28-13-17)22(33)15(3)26(36)39-23/h6-11,13,15-16,18,20,22,32-33H,5,12H2,1-4H3,(H,30,34)(H,31,35)/b23-14-/t15-,16-,18+,20+,22-/m1/s1
  • Molecular Formula: C27H32N4O8
  • Molecular Structure:CAS No:18791-21-4 Pyridomycin

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18791-21-4 Pyridomycin

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References of Pyridomycin
Title: Pyridomycin
CAS Registry Number: 18791-21-4
CAS Name: 3-Hydroxy-N-[(2Z,5R,6S,9S,10S,11R)-10-hydroxy-5,11-dimethyl-2-(1-methylpropylidene)-3,7,12-trioxo-9-(3-pyridinylmethyl)-1,4-dioxa-8-azacyclododec-6-yl]-2-pyridinecarboxamide
Molecular Formula: C27H32N4O8
Molecular Weight: 540.56
Percent Composition: C 59.99%, H 5.97%, N 10.36%, O 23.68%
Literature References: Antimycobacterial antibiotic substance produced by Streptomyces albidofuscus Okami et Umezawa, nov sp., renamed S. pyridomyceticus. Isoln: Maeda et al., J. Antibiot. 6A, 140 (1953); K. Yagishita, ibid. 7A, 143 (1954). Degradation studies: Maeda, ibid. 10A, 94 (1957). Structure: Koyama et al., Tetrahedron Lett. 1967, 3587; H. Ogawara et al., Chem. Pharm. Bull. 16, 679 (1968). Synthetic study: M. Kinoshita, M. Awamura, Bull. Chem. Soc. Jpn. 51, 869 (1978); M. Kinoshita et al., ibid. 3595. Production: JP 54 7048; JP 55 1349; JP 56 9566 (1954, 1955, 1956 all to Nippon Antibiotic Subst. Sci. Assoc.).
Properties: Crystals from ethanol, mp 222°. uv max (ethanol): 303 nm (E1%1cm 209). Soluble in lower alcohols, ethyl or butyl acetate, benzene, acetone, dioxane, tetrahydrofuran. Practically insol in water.
Melting point: mp 222°
Absorption maximum: uv max (ethanol): 303 nm (E1%1cm 209)
 
Derivative Type: Hydrochloride
Properties: Crystals, mp 194-196°. Freely sol in water. [a]D16 -53.2° (water). pH of aq solns about 2.0. LD50 i.p. in mice: >2100 mg/kg (Yagishita).
Melting point: mp 194-196°
Optical Rotation: [a]D16 -53.2° (water)
Toxicity data: LD50 i.p. in mice: >2100 mg/kg (Yagishita)