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CAS No 1873-77-4 , TRIS(TRIMETHYLSILYL)SILANE Search by region : China

  • Name: TRIS(TRIMETHYLSILYL)SILANE
  • Synonyms: TRIS(TRIMETHYLSILYL)SILANE;TRIS(TRIMETHYLSILYL)SILANE-D; 1,1,1,3,3-HEXAMETHYL-2-TRIMETHYLSILYL-TRISILANE; TRIS(TRIMETHYLSILYL)SILANE 97+%; TRIS(TRIMETHYLSILYL)SILANE 96%; Tris(trimethylsilyl)silane (stabilized with TBBP) [Reducing Reagent]; TTMSS; 1,1,1,3,3,3-HEXAMETHYL-2-(TRIMETHYLSILYL)TRISILANE;
  • CAS Registry Number:
  • Transport: UN 1993 3
  • Refractive index: n20/D 1.489(lit.)
  • Water Solubility: Insoluble in water
  • Safety Statements: R10-36/37/38,
  • Hazard Symbols: Xi:;
  • EINECS: -0
  • Molecular Weight: 248.66
  • InChI: InChI=1/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
  • Risk Statements: S16-26-36,
  • Molecular Formula: C9H28Si4
  • Molecular Structure:CAS No:1873-77-4 TRIS(TRIMETHYLSILYL)SILANE

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References of TRIS(TRIMETHYLSILYL)SILANE
Title: Tris(trimethylsilyl)silane
CAS Registry Number: 1873-77-4
CAS Name: 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)trisilane
Molecular Formula: C9H28Si4
Molecular Weight: 248.66
Percent Composition: C 43.47%, H 11.35%, Si 45.18%
Line Formula: ((CH3)3Si)3SiH
Literature References: Radical based mediator. Prepn: H. Gilman et al., Chem. Ind. (London) 1965, 848; H. Bürger, W. Kilian, J. Organomet. Chem. 18, 299 (1969). Si-H bond dissociation energies: J. M. Kanabus-Kaminska et al., J. Am. Chem. Soc. 109, 5268 (1987). Identification as reducing agent: C. Chatgilialoglu et al., J. Org. Chem. 53, 3641 (1988). Use as a reducing agent: M. Ballestri et al., ibid. 56, 678 (1991); D. H. R. Barton et al., Tetrahedron Lett. 33, 6629 (1992); in carbonylation: I. Ryu et al., Synlett 1993, 143.
Properties: Liquid, bp8mm 80-83°.
Boiling point: bp8mm 80-83°
Use: Reducing and hydrosilyating agent.