Home > Name List By other > (4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4, 5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde

CAS No 138-55-6 , (4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde

  • Name: (4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde
  • Synonyms: saffron-bitter; (R)-4-(beta-D-Glucopyranosyloxy)-2,6,6-trimethyl-1-cyclohexene-1-carboxaldehyde; UNII-E849G4X5YJ;(4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,
    5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde; AC1Q6BKI; 138-55-6;
  • CAS Registry Number:
  • Flash Point: 187.1°C
  • Boiling Point: 520.4°Cat760mmHg
  • Density: 1.31g/cm3
  • Refractive index: 1.561
  • Flash Point: 187.1°C
  • Molecular Weight: 330.37344
  • InchiKey: WMHJCSAICLADIN-WYWSWGBSSA-N
  • InChI: InChI=1S/C16H26O7/c1-8-4-9(5-16(2,
    3)10(8)6-17)22-15-14(21)13(20)12(19)11(7-18)23-15/h6,9,11-15,18-21H,4-5,
    7H2,1-3H3/t9-,11-,12-,13+,14-,15-/m1/s1
  • Molecular Formula: C16H26O7
  • Molecular Structure:CAS No:138-55-6 (4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,<br />5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde

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138-55-6 PICROCROCINE

  • Germany Cfm Oskar Tropitzsch [Manufacturer]
  • Tel: +49-9231-9619-0
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    Waldershofer Str. 49-51
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    Germany null,nullGermany
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138-55-6 1-Cyclohexene-1-carboxaldehyde,4-(b-D-glucopyranosyloxy)-2,6,6-trimethyl-,(4R)-

  • China Xi'an app-chem bio(tech) co.,ltd [Manufacturers]
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  • Address: Gazelle Valley,No.69,Jinye Road xi'an,shangxiChina
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References of (4R)-2,6,6-trimethyl-4-[(2R,3R,4S,5S,6R)-3,4,
5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carbaldehyde
Title: Picrocrocin
CAS Registry Number: 138-55-6
CAS Name: (4R)-4-(b-D-Glucopyranosyloxy)-2,6,6-trimethyl-1-cyclohexene-1-carboxaldehyde
Synonyms: saffron-bitter
Molecular Formula: C16H26O7
Molecular Weight: 330.37
Percent Composition: C 58.17%, H 7.93%, O 33.90%
Literature References: From stigmas of Crocus sativus L., Iridaceae. Isoln: Kayser, Ber. 17, 2228 (1884). Structure: Kuhn, Winterstein, Ber. 67, 344 (1934). Exerts sex-determining influences in the plant organism: Kuhn, Angew. Chem. 53, 1 (1940). Its moieties are glucose and safranal, q.q.v. Abs config: Buchecker, Eugster, Helv. Chim. Acta 56, 1121 (1973). Synthesis: H. Mayer, J.-M. Santer, Helv. Chim. Acta 63, 1463 (1980).
Properties: Crystals, mp 154-156°. [a]D20 -58° (c = 0.6). Bitter taste. Alkali unstable. Sol in water, alcohol; slightly sol in chloroform, ether. Practically insol in petr ether, benzene.
Melting point: mp 154-156°
Optical Rotation: [a]D20 -58° (c = 0.6)