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CAS No 116-09-6 , 1-hydroxypropan-2-one

  • Name: 1-hydroxypropan-2-one
  • Synonyms: 1-hydroxy-; Acetol; 1-Hydroxyacetone; 1-Hydroxy-2-propanone; Acetone alcohol;1-hydroxypropan-2-one; 1-hydroxypropan-2-one; Acetylmethanol; 116-09-6; 2-Propanone;Hydroxyacetone;
  • CAS Registry Number:
  • Transport: UN 1224
  • Melting Point: -17 ºC
  • Flash Point: 56 ºC
  • Boiling Point: 145-146 ºC
  • Density: 1.082
  • Refractive index: 1.425
  • Safety Statements: Moderately toxic by ingestion. Mutation data reported. An allergen. Implicated in aplastic anemia. A 10 gram dose may be fatal to an adult. Skin contact, inhalation, or ingestion can cause asthma, sneezing, irritation of eyes and nose, hives, and eczema. Combustible when exposed to heat or flame. When heated to decomposition it emits acrid smoke and fumes.
  • HS Code: 29144090
  • Flash Point: 56 ºC
  • EINECS: 204-124-8
  • Molecular Weight: 74.07854
  • InchiKey: XLSMFKSTNGKWQX-UHFFFAOYSA-N
  • InChI: InChI=1S/C3H6O2/c1-3(5)2-4/h4H,2H2,1H3
  • Risk Statements: S23;S24/25
  • Molecular Formula: C3H6O2
  • Molecular Structure:CAS No:116-09-6 1-hydroxypropan-2-one

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References of 1-hydroxypropan-2-one
Title: Acetol
CAS Registry Number: 116-09-6
CAS Name: 1-Hydroxy-2-propanone
Synonyms: hydroxyacetone; acetone alcohol; acetylcarbinol; acetylmethanol; 2-oxopropanol
Molecular Formula: C3H6O2
Molecular Weight: 74.08
Percent Composition: C 48.64%, H 8.16%, O 43.19%
Line Formula: H3CCOCH2OH
Literature References: Widely distributed in nature. Produced in animals as an intermediate in the intrahepatic metabolism of acetone. Also formed by the action of aldose reductase on methylglyoxal, q.v. and accumulates in uncontrolled diabetes. Prepn: W. H. Perkin, Jr., J. Chem. Soc. 59, 786 (1891); T. Matsumoto et al., J. Org. Chem. 50, 603 (1985). Isoln from coffee extract: M. Stoll et al., Helv. Chim. Acta 50, 628 (1967). HPLC determn in serum: J. P. Casazza, J. L. Fu, Anal. Biochem. 148, 344 (1985). Metabolism and potential role in diabetic complications: D. L. Vander Jagt et al., J. Biol. Chem. 267, 4364 (1992). Use in peptide synthesis: B. Kundu, Tetrahedron Lett. 33, 3193 (1992).
Properties: Colorless oil with peculiar odor. bp20 50°; bp200 105-106°; bp760 147° (dec). nD20 1.4235. d420 1.0872. Misc with water.
Boiling point: bp20 50°; bp200 105-106°; bp760 147° (dec)
Index of refraction: nD20 1.4235
Density: d420 1.0872
Use: Reagent in organic synthesis; protecting group for the synthesis of peptides.