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CAS No 110235-47-7 , 4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine

  • Name: 4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine
  • Synonyms: 4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine; 4-methyl-N-phenyl-6-(prop-1-ynyl)pyrimidin-2-amine;110235-47-7; 4-Methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine; Mepanipyrim [ISO];
  • CAS Registry Number:
  • Transport: UN 3077
  • Flash Point: 131 ºC
  • Density: 1.16 g/cm3
  • Refractive index: 1.617
  • Safety Statements: R51/53
  • Hazard Symbols: N: Dangerous for the environment;
  • Flash Point: 131 ºC
  • EINECS: 432-140-7
  • Molecular Weight: 223.27312
  • InchiKey: CIFWZNRJIBNXRE-UHFFFAOYSA-N
  • InChI: InChI=1S/C14H13N3/c1-3-7-13-10-11(2)15-14(17-13)16-12-8-5-4-6-9-12/h4-6,
    8-10H,1-2H3,(H,15,16,17)
  • Risk Statements: S60
  • Molecular Formula: C14H13N3
  • Molecular Structure:CAS No:110235-47-7 4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine

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References of 4-methyl-N-phenyl-6-prop-1-ynylpyrimidin-2-amine
Title: Mepanipyrim
CAS Registry Number: 110235-47-7
CAS Name: 4-Methyl-N-phenyl-6-(1-propynyl)-2-pyrimidinamine
Synonyms: 2-anilino-4-methyl-6-(1-propynyl)pyrimidine; N-(4-methyl-6-prop-1-ynylpyrimidin-2-yl)aniline
Manufacturers' Codes: KIF-3535; KUF-6201
Trademarks: Frupica (Kumiai)
Molecular Formula: C14H13N3
Molecular Weight: 223.27
Percent Composition: C 75.31%, H 5.87%, N 18.82%
Literature References: Antifungal for use in food crops; inhibits secretion of host-cell wall degrading enzymes. Prepn: S. Ito et al., EP 224339; eidem, US 4814338 (1987, 1989 both to Kumiai; Ihara); and biological activity: S. Hayashi et al., J. Pestic. Sci. 22, 165 (1997). Fungicidal activity and field trials: S. Maeno et al., Brighton Crop Prot. Conf. - Pests Dis. 1990, 415. Mode of action study: I. Miura et al., Pestic. Biochem. Physiol. 48, 222 (1994). GC-MS determn in grapes, must and wine: P. Cabras et al., J. AOAC Int. 81, 1185 (1998). Metabolism in tomato seedlings: M. Ikeda et al., J. Pestic. Sci. 23, 9 (1998).
Properties: White solid with two crystalline modifications. mp 125-126° (Maeno); also reported as 132.8° (Hayashi). Specific gravity 1.2025. Soly in water at 20°: 5.58 mg/l. Sol in most organic solvents. Vapor pressure at 20°: 1.03 ′ 10-5 torr. Log P (octanol/water): 3.42. LD50 in mice, rats, bobwhite, mallard (mg/kg): >5000, >5000, >2250, >2250 orally; in rats (mg/kg): >2000 dermally. LC50 in bluegill, rainbow trout (mg/l): 3.8, 3.1 (Maeno).
Melting point: mp 125-126° (Maeno); also reported as 132.8° (Hayashi)
Log P: Log P (octanol/water): 3.42
Toxicity data: LD50 in mice, rats, bobwhite, mallard (mg/kg): >5000, >5000, >2250, >2250 orally; in rats (mg/kg): >2000 dermally; LC50 in bluegill, rainbow trout (mg/l): 3.8, 3.1 (Maeno)
Use: Agricultural fungicide.