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CAS No 107-32-4 , Methaneperoxoic acid(9CI)

  • Name: Methaneperoxoic acid(9CI)
  • Synonyms: Peroxyformicacid (6CI,8CI); Formyl hydroperoxide; Permethanoic acid; Performic acid;Methaneperoxoic acid(9CI);
  • CAS Registry Number:
  • Flash Point: 67.5°C
  • Boiling Point: 127.5°Cat760mmHg
  • Density: 1.341g/cm3
  • Refractive index: 1.357
  • Safety Statements: A powerful irritant and an oxidizer. A dangerous fire hazard when exposed to heat, flame, or reducing materials. Unstable and shock-sensitive. 80% solution is explosive. Extremely dangerous when moved. Violent reaction with carbon, red phosphorus, silicon, formaldehyde, benzaldehyde, aniline, alkenes. Self-reactive. Incompatible with metals, nonmetals, organic materials. When heated to decomposition it emits acrid smoke and irritating fumes.
  • Flash Point: 67.5°C
  • Molecular Weight: 0
  • InChI: InChI=1/CH2O3/c2-1-4-3/h1,3H
  • Molecular Formula: CH2O3
  • Molecular Structure:CAS No:107-32-4 Methaneperoxoic acid(9CI)

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References of Methaneperoxoic acid(9CI)
Title: Performic Acid
CAS Registry Number: 107-32-4
CAS Name: Methaneperoxoic acid
Synonyms: peroxyformic acid; permethanoic acid; formyl hydroperoxide
Molecular Formula: CH2O3
Molecular Weight: 62.02
Percent Composition: C 19.37%, H 3.25%, O 77.39%
Line Formula: HCOOOH
Literature References: A strong oxidizing agent. A 90% soln is obtained when a mixture of 20 g formic acid, 25 g 100% H2O2 and 6.5 g H2SO4 is allowed to interact for 2 hrs and is then distilled: D'Ans, Kneip, Ber. 48, 1137 (1915); Greenspan, J. Am. Chem. Soc. 68, 907 (1946).
Properties: The 90% soln is a colorless liq. Prone to explode on contact with metals, their oxides, reducing substances, or on distillation. Has lower vapor pressure than formic acid. Miscible with water, alc, ether. Sol in benzene, chloroform. Solns are unstable, gassing being noticeable after a few hours, and the effective concn showing a definite decline in 2 hrs.
CAUTION: Irritant.
Use: For oxidation, epoxidation and hydroxylation reactions.