Title: Acrinathrin
CAS Registry Number: 101007-06-1
CAS Name: (1
R,3
S)-2,2-Dimethyl-3-[(1
Z)-3-oxo-3-[2,2,2-trifluoro-1-(trifluoromethyl)ethoxy]-1-propenyl]cyclopropanecarboxylic acid (
S)-cyano(3-phenoxyphenyl)methyl ester
Synonyms: (
S)-a-cyano-3-phenoxybenzyl (1
R-
cis)-2,2-dimethyl-3-[(
Z)-3-oxo-3-[2-(1,1,1,3,3,3-hexafluoropropoxy)]-1-propenyl]cyclopropanecarboxylate
Manufacturers' Codes: RU-38702
Trademarks: Rufast (AgrEvo)
Molecular Formula: C26H21F6NO5
Molecular Weight: 541.44
Percent Composition: C 57.68%, H 3.91%, F 21.05%, N 2.59%, O 14.77%
Literature References: Synthetic pyrethroid acaricide. Prepn: J. Martel
et al., FR 2486073;
eidem, US 4542142 (1982, 1985 both to Roussel-UCLAF); J. R. Tessier
et al., in
Pesticide Chemistry: Human Welfare and the Environment vol. 1, J. Miyamoto, P. C. Kearney, Eds. (Pergamon Press, Oxford, 1983) pp 95-100. Field trial vs spider mite: B. H. Labanowska, C. Tkaczuk,
Fruit Sci. Rep. 18, 185 (1991).
Review: J. J. Heller
et al., Meded. Fac. Landbouwwet. Univ. Gent 57, 931-939 (1992).
Properties: mp 82°. [a]D20 +23.5° (c = 0.5% in benzene). LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Heller).
Melting point: mp 82°
Optical Rotation: [a]D20 +23.5° (c = 0.5% in benzene)
Toxicity data: LD50 in rats (mg/kg): >5000 orally; >2000 dermally (Heller)
Use: Insecticide.